Effect of particle size of Y2O3-Al2O3 additives on microstructure and mechanical properties of Si3N4 ceramic balls for bearing applications

Abstract

Si3N4 ceramic balls were prepared by gas pressure sintering with Y2O3 and Al2O3 as sintering additives. The effects of particle size of Y2O3-Al2O3 additives on densification, microstructure and mechanical properties of Si3N4 ceramic balls were investigated. The reliability of Si3N4 ceramic balls was evaluated through the Weibull modulus. The results showed that Si3N4 ceramic balls containing nanosized Y2O3-Al2O3 additives have a higher relative density and better comprehensivemechanical properties compared with the samples containing microsized additives, with relative density of 98.9 ? 0.2%TD, Vickers hardness of 14.7 ? 0.1GPa, indentation fracture toughness of 6.5 ? 0.1MPa?m1/2 and crushing strength of 254 ? 8.5MPa. The more homogeneous and extensive dispersion of the nanosized sintering additives in the Si3N4 matrix is the main reason for the enhancement in density and mechanical properties of the Si3N4 ceramic balls.

Phase homogeneity of Si3N4-based ceramic materials produced by spark plasma sintering

“…To resolve this problem, sintering additives of various compositions are used, e.g. the Y 2 O 3 −Al 2 O 3 [3] system. In the process of sintering the α-Si 3 N 4 phase is dissolved in the phase of sintering additive, and then it crystallizes in the form of β-Si 3 N 4 .…”