11A key issue associated with Fluidized Bed Combustion of biomass is agglomeration. The presence of 12 high quantities of alkali species in biomass ash leads to the formation of sticky alkali-silicate liquid 13 phases during combustion, and consequently the adhesion and agglomeration of bed material. This 14 review principally examines probable mechanisms of agglomeration and the effects of operational 15 variables in reducing its severity. Additionally, an overview of monitoring and prediction of 16 agglomerate formation is given. Two key mechanisms of agglomeration are apparent in literature, 17 and both may occur concurrently dependent on fuel composition. Coating-induced agglomeration is 18 defined by the interaction of alkali metals in fuel ash with the bed material, commonly silica sand, to 19 form an alkali-silicate melt. Melt-induced agglomeration is defined by the presence of sufficient 20 amounts of both alkali compounds and silica liquid phases sourced from the fuel ash to form a 21 eutectic mixture. Physical mechanisms, such as tumble agglomeration and sintering, may further 22 enhance either of the coating-induced or melt-induced mechanisms. Of the operational variables volumes of non-combustible contaminants, high moisture contents and, in most applications, 63 requires a large amounts of pre-processing/pre-treatment with specialised transportation. Due to 64 these challenges, technologies such as fluidized bed combustion (FBC) boilers have been employed. 65 FBC offers a number of advantages, such as combustion of different fuel types, blends, and ranges of 66 qualities, features commonly referred to under the umbrella term of [5]. Hundreds 67 Page 4 of 75 of full-scale bubbling fluidized bed (BFB) [6, p. 7] and circulating fluidized bed (CFB) [6, p. 8] boilers 68have been deployed around the world [7, 8] for power generation and/or steam sales to industrial or 69 chemical plant sites. However, each FBC plant development has to overcome slagging, fouling, 70 corrosion and, most significantly, agglomeration issues resulting from the composition and 71 behaviour of the biomass fuel stock [9]. 72