“…Surface modification of surgical implants by sol gel coatings has been proposed as a tool to generate a surface that besides being protective could also allow the integration of the metal to the human body, generating a ''bioactive'' interface that has the ability of create a natural bonding between the metal surface and the existing bone. It has been demonstrated that inorganic -hybrid SiO 2 coatings, obtained from tetraethylorthosilicate (TEOS) and methyltriethoxysilane (MTES) improve the corrosion behaviour of the AISI 316L stainless steel in biological environments (Ballarre et al, 2007;Checmanowski and Szczygiel, 2008;Chou et al, 2003). The hybrid layers of TEOS and other silanes are not bioactive per se but if the coatings are also functionalized with a bioactive ceramic or glass-ceramic from the CaO-SiO 2 -P 2 O 5 system, it has been proved that the HA rate can be maximized (Höland, 1997;Kokubo et al, 1992;Peitl et al, 2001).…”