Effect of Mussel‐Inspired Poly(Dopamine)‐Functionalized Carbon Nanotubes/Graphene Nanohybrids on Interfacial Adhesion of Soy Protein‐Based Nanocomposites

Abstract

The demands for strong integrated biopolymer materials have substantially increased across various industries. In this study, a biomimic strategy was proposed to prepare the poly(dopamine)‐functionalized carbon nanotubes (PDCNTs) via mussel‐inspired chemistry. The graphene dispersion was prepared in aqueous bovine serum albumin solution by ultrasonic treatment through a facile and green approach. Inspired by the excellent integration of mechanical properties and hierarchical nano/microscale structure of natural nacre, we fabricated soy isolate protein (SPI)‐based nanocomposite film with 2D graphene nanosheets and 1D surface‐functionalized PDCNTs through a layer‐by‐layer assembly process. The morphology and thickness of graphene nanosheets were analyzed by atomic force microscopy. The successful surface modification of PDCNTs was confirmed by X‐ray photoelectron spectroscopy and transmission electron microscopy. The cross‐linking hierarchical structure of the SPI hybrid film was observed in scanning electron microscopy images. A combination of multiple interfacial interactions and enhanced adhesion between the PDCNTs‐graphene conjugation and SPI matrix resulted in a remarkable improvement in the mechanical properties of the SPI‐based nanocomposites. When compared with the unmodified film, the tensile strength and elongation at break of the hybrid film were simultaneously increased by 158.93 and 78.67%, respectively. As a result of the enhanced tortuosity effect, the water vapor permeability was significantly reduced by 33.65%. In addition, the resultant film also possessed favorable water resistance, thermal stability, and ultraviolet–visible light barrier behavior. This work provided a novel bio‐inspired interfacial toughening strategy for constructing high performance biopolymer nanocomposites. POLYM. COMPOS., 40:E1649–E1661, 2019. © 2018 Society of Plastics Engineers

A mussel‐inspired strategy toward antimicrobial and bacterially anti‐adhesive soy protein surface

“…In the case of S‐DA‐Ag film, the less MA at a slower rate was observed than that of the S‐DA film. The loading of AgNPs increased the roughness of the film surface and created a more tortuous path for the water molecules permeating into the SPI‐based film, thereby reducing the water absorption of S‐DA‐Ag film . In particular, the OTS‐loading SPI films exhibited a water absorption of less than 20% before absorption equilibrium.…”

“…Pathogenic microbial infections have been on the rise in staggering numbers over the past years. Meanwhile, microorganisms may cause the decomposition, corrosion, and deterioration of matrix materials, which increases energy and fuel costs . Therefore, endowing a surface of implanted medical devices, daily commodities, or equipment with antimicrobial property is extremely necessary in the applications of health care, packaging, water purification, marine biofouling, and textile industry .…”

Frequency‐dependent dynamic moduli prediction for general bio‐inspired staggered platelet reinforced composites

“…Such an exceptional combination of mechanical properties like high stiffness and toughness caught scientists' eyes worldwide [15,16] and promoted the design and fabrication of such bio-inspired materials. [10,17] After decades of exploration, both the research and the application of those biomaterials have been deeply developed. Those biomaterials show great potential in areas of lightweight engineering materials, especially for impact resistant armor materials and damage tolerant components.…”