Unique spindle microstructures with
an apex angle of ∼20°
bring the ability of directional water collection to various biosystems
(i.e., spider silk and cactus stem). This has great potential to solve
the insufficient interfacial wetting for mechanical interlocking formation
between polymers and substrates. In this study, the bioinspired spindle
microstructures were easily fabricated through the deposition of molten
materials by a nanosecond laser with an overlap ratio of 21% between
laser spots and achieved superior interfacial wetting for commercial
epoxy adhesive on aluminum substrates. Detailed analyses show that
there are four mechanisms responsible for the superior interfacial
wettability of bioinspired spindle microstructures: the Laplace pressure
difference, newly formed aluminum oxide, the capillary effect, and
no extra pressure from a trapped atmosphere. Consequently, the bioinspired
spindle surface microstructures achieve a maximum improvement of ∼16
and ∼39% in interfacial bonding strength before and after water
soak exposure compared to the as-received condition. Moreover, the
stable interfacial wettability of bioinspired spindle microstructures
ensures that the improved joint strength varied little with an increase
in surface roughness from ∼1.7 to ∼12.8 μm. However,
the interfacial wettability of common dimple microstructures deteriorated
with an increase in surface roughness, which is indicated by the decreasing
rule in the quadratic polynomial function of the interfacial bonding
strength as the surface roughness increases from ∼2.1 to ∼18.2
μm.