Effect of K+ and Ca2+ Cations on Structural Manganese(IV) Oxide for the Aerobic Oxidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic Acid
Thinnaphat Poonsawat,
Peerapong Promcharoen,
Titiya Meechai
et al.
Abstract:The promising influences of K
+
and Ca
2+
ions
in the development of effective MnO
2
for the selective
oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid
(FDCA) were studied for the catalytic performance under a high-pressure
reaction of aqueous O
2
(0.5 MPa) in a basic system. Various
oxidation states of manganese in MnO
2
were able to accelerate
the oxidation of 5-formyl-2-furanc… Show more
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