A double layer 2-terminal
device is employed to show Na-controlled
interfacial resistive switching and neuromorphic behavior. The bilayer
is based on interfacing biocompatible NaNbO3 and Nb2O5, which allows the reversible uptake of Na+ in the Nb2O5 layer. We demonstrate
voltage-controlled interfacial barrier tuning via Na+ transfer,
enabling conductivity modulation and spike-amplitude- and spike-timing-dependent
plasticity. The neuromorphic behavior controlled by Na+ ion dynamics in biocompatible materials shows potential for future
low-power sensing electronics and smart wearables with local processing.