Effect of Inorganic Ions on the Discoloration of Rhodamine B by the Fenton Process

Abstract

This study showed that the oxidation of rhodamine B by the Fenton process is a very fast method because the reaction takes place within the first 20 minutes. The mixture of Fe2+ and H2O2 produces hydroxide radicals responsible for the degradation of rhodamine B. The study of pH influence on the rhodamine B oxidation reveals that for maximum oxidation of rhodamine B, the pH must be less than or equal to 2. For pH > 2, there is a decrease in rhodamine B oxidation. This is due to side reactions that occur if the concentration of Fe2+ is high. This reduces the amount of oxidized rhodamine B. We note that the oxidation of rhodamine B is faster for low concentrations than for high concentrations of rhodamine B. According to our results, for a maximum oxidation of 5 mg / L of rhodamine, it takes 8.4.10−4 mg / L of Fe2+, 3.10−3 M of H2O2 and pH = 2. This work also showed that the presence of inorganic ions strongly slows down the rate of degradation of rhodamine in the following order: Cl− ˂ NO3− ˂ SO42− ˂ PO43−.