“…Increase in ρ is due to a change in the proportion of free volume and to ordering of the structure of PVB systems. Reduction in ρ is caused by deformation of the structure of PVB systems to a level where rearrangement of the short-range order no longer occurs, which generates segmental suppression, complications in processes of rearrangement and packing of macrochains, and the formation of microdefects at higher levels of compression moulding and fi lling [6].…”