Hot-work die steels are widely used in the hot-working molds of pressing and molding metal parts at high temperatures. [1][2][3] When hot-work die steel interacts directly with hot metal, it not only bears heavy mechanical loads but also needs to bear rapid heating and cooling impact. [4] In many cases, the temperature of the mold surface may exceed 500 °C or even higher, which will inevitably lead to the continuous evolution of microstructure. In turn, the microstructure evolution will affect the performance of the mold, such as hardness, strength, and toughness during service life. [5] Therefore, combining good mechanical properties at service temperature is necessary for hot-work die steel.It has been accepted that the comprehensive properties of hot-work die steels are mainly dominated by the chemical composition, manufacturing methods, and heat-treatment process. For example, H13 hot-work die steel is a typical hot-work die steel, which has been widely investigated. However, the ultimate strength decreased from more than 1700 to about 600 MPa at the temperature of 640 °C of H13 steel, and even less than 300 MPa at 700 °C, which greatly deteriorated the service life. [6][7][8] Therefore, researchers have carried out work on the development and optimization of hot-work die steel. Zhang et al. [3] studied a newly designed V-containing hot-work die steel (MPS700V) that the ultimate tensile strength (UTS) at room temperature increased from 1127 to 1442 MPa, and the UTS at 700 °C increased from 400 to 550 MPa. Chen et al. [9] studied that the impact energy, hardness, and UTS improved significantly in the rare earth (RE) modified H13 die steel. Adding nitrogen can improve the strength of die steel without loss of toughness, and can also improve the corrosion resistance of die steel. [10][11][12] Li et al. [13] reported that adding nitrogen to H13 steel could significantly improve the impact toughness and hardness. Gu et al. [14] drew a similar conclusion by researching nitrogen alloyed 4Cr5Mo2V hot-working die steel. In addition, several studies had researched elements addition (such as RE and Mg) to modify the inclusion and precipitate types to improve the cleanness and properties. [9,15] The heat treatment process is also applied to the hot-work die steel, such as annealing, [16,17] austenitizing, [18,19] tempering, [4,20] and cryogenic treatment. [21,22] Furthermore, electroslag remelting (ESR) process is also applied to manufacturing high-quality hot-work die steel since it could enhance cleanness and solidification structure. [23][24][25]