With the increasing mining depths and the improving mining mechanization, coal miners in China have been exposed to increasingly hotter working conditions, especially in the working face where heat hazards are of high possibility. In this paper, a multi-segment thermos physiological model with an improvement in heat and moisture transfer through clothing was used to evaluate heat stress at the working face in hot coal mines. The improved thermos physiological model was firstly demonstrated with miners' thermal response data collected by field measurements, and then parametric simulations were done to evaluate the physiological influences of the relative humidity and the unsteady (cool-hot changing) air temperature along the working face. It is found that the cool-hot changing thermal environments significantly affect miners' physiological responses and thermal sensations, especially the air temperature changes around 24 o C~26 o C, and the heat stress can be relieved if a proper work-rest organization in a hot working face is addressed