Effect of He on the Order-Disorder Transition in Ni3Al under Irradiation

Abstract

The order-disorder transition in Ni-Al alloys under irradiation represents an interplay between various re-ordering processes and disordering due to thermal spikes generated by incident high energy particles. Typically, ordering in enabled by diffusion of thermally-generated vacancies, and can only take place at temperatures where they are mobile and in sufficiently high concentration. Here, in-situ transmission electron micrographs reveal that the presence of He-usually considered to be a deleterious immiscible atom in this material-promotes reordering in Ni3Al at temperatures where vacancies are not effective ordering agents. A rate-theory model is presented, that quantitatively explains this behavior, based on parameters extracted from atomistic simulations. These calculations show that the V2He complex is an effective agent through its high stability and mobility. It is surmised that immiscible atoms may stabilize reordering agents in other materials undergoing driven processes, and preserve ordered phases at temperature where the driven processes would otherwise lead to disorder.

Effects of helium on irradiation-induced phase instability in a NiCrFeTiNbAl alloy

“…In parallel with this experimental study, the current research group also carried out a rate-theory model and computer calculation. The theoretical work has been published separately and quantitatively explains this behaviour [38]. Calculations indicated that the V 2 He complex might play an effective role through its high stability and mobility, so helium atoms may stabilize reordering agents during irradiation at certain temperatures where the irradiation would lead to the disordering of γ' precipitates.…”