2007
DOI: 10.1016/j.jlumin.2006.01.106
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Effect of grain size and concentration of active ions on structural and optical behavior of Eu3+-doped Y3Al5O12 nanocrystallites

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Cited by 28 publications
(15 citation statements)
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“…Broad peaks centered around 460 and 344 nm are characteristic of transitions between 4f 1 ground state ( 2 F 5/2 and 2 F 7/2 levels) to two lower energy crystal field split 5d states of Ce 3+ ions. The difference in energy between the two excited sates matches well with that reported for Ce 3+ ions in YAG host [9,10]. Further the pattern also consists of a relatively sharp peak around 277 nm.…”
Section: Article In Presssupporting
confidence: 86%
See 1 more Smart Citation
“…Broad peaks centered around 460 and 344 nm are characteristic of transitions between 4f 1 ground state ( 2 F 5/2 and 2 F 7/2 levels) to two lower energy crystal field split 5d states of Ce 3+ ions. The difference in energy between the two excited sates matches well with that reported for Ce 3+ ions in YAG host [9,10]. Further the pattern also consists of a relatively sharp peak around 277 nm.…”
Section: Article In Presssupporting
confidence: 86%
“…Yellow light emission from YAG:Ce phosphor arises due to 5d-4f transition of Ce 3+ . This transition is very sensitive to presence of other lanthanide ions in the host and conditions employed for their synthesis [7][8][9][10]. For example codoping bulk YAG:Ce with Eu 3+ and Mn 2+ ions results in a significant decrease in luminescence intensity of 5d-4f transition of Ce 3+ ions [8].…”
Section: Introductionmentioning
confidence: 99%
“…Moreover, the bands in the 600-630 nm wavelength range can be assigned to ED-allowed 5 D 0 → 7 F 2 transitions. The present attribution is also in agreement with the results obtained for an Eu 3+ -doped YAG single crystal [39] and for nanocrystalline Eu 3+ -doped YAG powders [40,41]. Besides, the luminescence spectrum is similar to that observed for an Eu 3+ -doped GGG [39]) and also for a Eu 3+ doped nanocrystalline GGG sample prepared by the Pechini method (about 160 cm −1 [43]).…”
Section: Eusupporting
confidence: 91%
“…Để hạn chế những nhược điểm này của phản ứng pha rắn, rất nhiều các phương pháp đã được nghiên cứu để tổng hợp YAG hoặc bột huỳnh quang trên nền YAG như phương pháp đốt cháy [5], solgel [6], phương pháp Pechini [7], phương pháp kết tủa [8][9][10][11] ) được tổng hợp theo phương pháp đồng kết tủa sử dụng dung dịch NH 3 làm tác nhân tạo kết tủa (Hình 1), theo đó các nguyên liệu ban đầu (bột europi oxit, bột yttri oxit và muối nhôm nitrat) được hòa tan vào nhau theo tỉ lệ về số mol 5:3 của ion Al 3+ và Y 3+ trong dung dịch axit nitric 65 %. Các hỗn hợp này được trộn đều với nhau trên máy khuấy từ gia nhiệt cho đến khi thu được dung dịch trong suốt.…”
Section: Mở đầUunclassified