Effect of Gold Nanoparticles on Fluorescence Properties of Hyperbranched Poly(amido amine)s

Abstract

Hyperbranched poly (amino amine) s (HPAMAMs), synthesized by Michael addition of 1-(2-aminoethyl) piperazine (AEPZ) and methyl acrylate (MA), can emit blue fluorescence under excitation wavelength. However, the relatively weak fluorescence of HPAMAMs is still an obstacle for its practical applications. Gold is one of the most frequently used metals for fluorescence enhancement. In this research, the influence of gold nanoparticles on fluorescence property of HPAMAMs was investigated by fluorometry. It was found that gold nanoparticles (GNPs) with smaller size (< 5 nm) presented greatly enhanced emission. The GNPs with larger size (~10 nm in diameter) and definite surface plasmon absorption can quench the fluorescence of HPAMAMs.