Co/Pt multilayer films with perpendicular magnetic anisotropy and large out-of-plane coercivities of 3.9 -8.5 kOe have been found to undergo a spin reorientation transition from out-of-plane to in-plane upon irradiation with 700 keV nitrogen ions. X-ray reflectivity experiments show that the multilayer structure gets progressively disrupted with increasing ion dose, providing direct evidence for local atomic displacements at the Co/Pt interfaces. This effectively destroys the magnetic interface anisotropy, which was varied by about a factor of two, between K S ≅ 0.4 erg/cm 2 and K S ≅ 0.85 erg/cm 2 for two particular films. The dose required to initiate spinreorientation, 6⋅1014 N +