“…Meanwhile, the d 0 0 1 reflection for basal spacing of the minerals in the XRD pattern did not suffer a significant change (Fig. S4 in the SM), indicating that FA and HA molecules did not significantly intercalate the mineral layers even for the 2:1 type of smectite and vermiculite [30]. Ligand exchange-surface complexation might be another important mechanism for FA/HA adsorption on the minerals.…”
Section: Mechanism Analysismentioning
confidence: 97%
“…7). The Fe 2p photoelectron spectra showed that the binding energy shifted toward lower energy by 0.10 and 0.19 eV for HA-and FA-vermiculite complexes compared with that of the original vermiculite, indicative a transfer of the electronic density from FA/HA to iron cation [30]. FA with lower molecular weight was easier than HA to get into close contact with vermiculite surface [8] and acted as a stronger -donor role than HA.…”
“…Meanwhile, the d 0 0 1 reflection for basal spacing of the minerals in the XRD pattern did not suffer a significant change (Fig. S4 in the SM), indicating that FA and HA molecules did not significantly intercalate the mineral layers even for the 2:1 type of smectite and vermiculite [30]. Ligand exchange-surface complexation might be another important mechanism for FA/HA adsorption on the minerals.…”
Section: Mechanism Analysismentioning
confidence: 97%
“…7). The Fe 2p photoelectron spectra showed that the binding energy shifted toward lower energy by 0.10 and 0.19 eV for HA-and FA-vermiculite complexes compared with that of the original vermiculite, indicative a transfer of the electronic density from FA/HA to iron cation [30]. FA with lower molecular weight was easier than HA to get into close contact with vermiculite surface [8] and acted as a stronger -donor role than HA.…”
“…The values of calculated Q and b are listed in Table 4. As stated by Wu et al, (2011), negative values of Q and b signify that the surface of Zeliac TM has heterogeneous coverage instead of monolayer coverage. Interestingly, analysis of the experimental data using non-linear equation of Langmuir isotherm gave an opposite explanation, where positive values of both Q and b were obtained.…”
Section: Adsorption Isothermsmentioning
confidence: 96%
“…As a consequence, the price of activated carbon keeps increasing because of high demand. Therefore, several studies (Lafi et al, 2014;Krishni et al, 2014;Chan et al, 2012;Wu et al, 2011) have been conducted to search or develop new media that are comparable to activated carbon. In the meantime, the composite of activated carbon and zeolite shows a promising potential as alternative adsorbents (Foo and Hameed, 2011).…”
The composite media, Zeliac TM was developed with the initial aim to provide low cost adsorbent with promising adsorption capacity. This study was conducted to investigate the removal of UV absorbance at 254 nm (UV254) in Kerian river water using Zeliac TM as the media. Batch experiments study was carried out to determine the optimum removal of UV254 by Zeliac TM . The experimental data were fitted to Langmuir and Freundlich isotherms to investigate the adsorption mechanism. The results from batch study exhibit that Zeliac TM is capable to remove 74.4% UV254 at the dosage of 7g/100 ml. Linear isotherm analysis suggests that the best fitting linear line is Freundlich isotherm with R 2 values of 0.9294 indicating multilayer adsorption. Similarly, non-linear regression analysis reveals that the adsorption of UV254 by Zeliac TM is attributed by physisorption. The non-linear Freundlich isotherm gives a better fit to the adsorption of UV254 than Langmuir isotherm with R 2 values of 0.9488. The results are supported with low values of X 2 , ARE, HYBRID and MPSED from the error function analysis. Additionally, it is noted that the linear analysis overestimates the constant parameters' values for Freundlich isotherm, which cause larger errors as estimated by the error function analysis. Hence, non-linear analysis is more appropriate in explaining the batch experiment data.
“…For example, when these chemical reach soils, they will be preferentially adsorb on bioavailable organic components, such as humic substances (Wu et al, 2011). Also, they can be absorbed by plants and living organisms.…”
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