Abstract:In this thesis, proper amount of whiskers were added to building gypsum used as the basic materials. The gypsum board properties, such as densities and flexural strength etc., were influenced by various whisker content. The results showed that the flexural performance of gypsum board could be enhanced when adding calcium sulfate whisker from a range of 0.5~3 wt.%. The flexural strength reached 5.38 MPa when calcium sulfate whisker content was 1 wt.%. The flexural strength could be higher than that of gypsum bo… Show more
“…In addition, with an increase in CSW dosage, the fatigue life of RFAC under the same stress level presented a trend of increasing and then decreasing, consistent with the trend observed in the static loading test. This is because when the amount of CSW is too large, the excessive microfiber cannot be uniformly distributed and may even cause agglomeration [43], leading to insufficient densification of the specimen and the formation of more pore spaces, thus decreasing the concrete's ability to withstand cyclic loading.…”
Section: Life Distribution Function Of Three-parameter Weibull Distri...mentioning
confidence: 99%
“…Therefore, when CSW is well-dispersed in the RFAC specimen, the increase in CSW per unit volume allows more whiskers to participate in the crack arresting effect. However, when the dosage of CSW is too high, due to the increased interactions between whiskers, the resistance of whiskers in the dispersion process increases [34,43], resulting in insufficient dispersion of whiskers and the whisker aggregation phenomenon occurring inside the test block. This loose accumulation of whiskers leads to a decrease in the densification of concrete, accelerating the expansion of the cracks under the action of cyclic loading and negatively affecting the fatigue performance of the CSWRF.…”
Section: The Action Mechanism Of Csw In Rfacmentioning
In order to study the flexural fatigue resistance of calcium sulfate whisker-modified recycled fine aggregate concrete (RFAC), flexural fatigue cyclic loading tests at different stress levels (0.6, 0.7, and 0.9) considering a calcium sulfate whisker (CSW) admixture as the main influencing factor were designed. Furthermore, the fatigue life was analyzed, and fatigue equations were established using the three-parameter Weibull distribution function theory. In addition, the micro-morphology of CSW-modified recycled fine aggregate concrete was observed and analyzed through Scanning Electron Microscopy (SEM), and the strengthening and toughening mechanisms of CSW on recycled fine aggregate concrete were further explored. The test results demonstrate that the inclusion of recycled fine aggregate reduces the fatigue life of concrete, while the incorporation of CSW can effectively improve the fatigue life of the recycled fine aggregate concrete, where 1% of CSW modification can extend the fatigue life of recycled fine aggregate concrete by 56.5%. Furthermore, the fatigue life of concrete under cyclic loading decreases rapidly as the maximum stress level increases. Fatigue life equations were established with double logarithmic curves, and P-S-N curves considering different survival probabilities (p = 0.5, 0.95) were derived. Microscopic analyses demonstrate that the CSW has a “bridging” effect at micro-seams in the concrete matrix, delaying the generation and enlargement of micro-cracks in the concrete matrix, thus resulting in improved mechanical properties and flexural fatigue resistance of the recycled fine aggregate concrete.
“…In addition, with an increase in CSW dosage, the fatigue life of RFAC under the same stress level presented a trend of increasing and then decreasing, consistent with the trend observed in the static loading test. This is because when the amount of CSW is too large, the excessive microfiber cannot be uniformly distributed and may even cause agglomeration [43], leading to insufficient densification of the specimen and the formation of more pore spaces, thus decreasing the concrete's ability to withstand cyclic loading.…”
Section: Life Distribution Function Of Three-parameter Weibull Distri...mentioning
confidence: 99%
“…Therefore, when CSW is well-dispersed in the RFAC specimen, the increase in CSW per unit volume allows more whiskers to participate in the crack arresting effect. However, when the dosage of CSW is too high, due to the increased interactions between whiskers, the resistance of whiskers in the dispersion process increases [34,43], resulting in insufficient dispersion of whiskers and the whisker aggregation phenomenon occurring inside the test block. This loose accumulation of whiskers leads to a decrease in the densification of concrete, accelerating the expansion of the cracks under the action of cyclic loading and negatively affecting the fatigue performance of the CSWRF.…”
Section: The Action Mechanism Of Csw In Rfacmentioning
In order to study the flexural fatigue resistance of calcium sulfate whisker-modified recycled fine aggregate concrete (RFAC), flexural fatigue cyclic loading tests at different stress levels (0.6, 0.7, and 0.9) considering a calcium sulfate whisker (CSW) admixture as the main influencing factor were designed. Furthermore, the fatigue life was analyzed, and fatigue equations were established using the three-parameter Weibull distribution function theory. In addition, the micro-morphology of CSW-modified recycled fine aggregate concrete was observed and analyzed through Scanning Electron Microscopy (SEM), and the strengthening and toughening mechanisms of CSW on recycled fine aggregate concrete were further explored. The test results demonstrate that the inclusion of recycled fine aggregate reduces the fatigue life of concrete, while the incorporation of CSW can effectively improve the fatigue life of the recycled fine aggregate concrete, where 1% of CSW modification can extend the fatigue life of recycled fine aggregate concrete by 56.5%. Furthermore, the fatigue life of concrete under cyclic loading decreases rapidly as the maximum stress level increases. Fatigue life equations were established with double logarithmic curves, and P-S-N curves considering different survival probabilities (p = 0.5, 0.95) were derived. Microscopic analyses demonstrate that the CSW has a “bridging” effect at micro-seams in the concrete matrix, delaying the generation and enlargement of micro-cracks in the concrete matrix, thus resulting in improved mechanical properties and flexural fatigue resistance of the recycled fine aggregate concrete.
“…As reinforcement materials, CaSO 4 ·0.5H 2 O whiskers with high length/diameter ratios, the synthesis of which has attracted much attention, have high strength and high application value in fields such as plastics. To obtain CaSO 4 ·0.5H 2 O whiskers with high aspect ratios, many researchers have conducted exploratory experiments on factors such as temperature, reaction time, and the organic or inorganic components added for the precipitation and dissolution of CaSO 4 ·0.5H 2 O whiskers. However, the loss of water from CaSO 4 ·2H 2 O and CaSO 4 ·0.5H 2 O results in a decrease in the whisker aspect ratio from a microscale perspective, the result of which is that a very fine powder, which cannot enhance or toughen the matrix material, is formed on the macro level .…”
Nano-CaSO4, a good cubic structure with dimensions of no more than 100 nm, was first prepared
from phosphogypsum (PG). The effects of different reaction conditions
on PG morphology, achieved by optimizing the reaction temperature,
the concentrations of HNO3, H2SO4, and cetyltrimethylammonium bromide (CTAB) and other factors, were
discussed. PG dissolved in HNO3 was reassembled after c-axis growth was inhibited by the common ion effect of
SO4
2–. The morphology of CaSO4 was regulated by a guiding agent, namely, a mixed solution of glycerol,
ethanol, and CTAB. The optimal morphological conditions of a smooth
surface and structural integrity were established at 140 °C.
The solid–liquid ratio of PG, CTAB, HNO3, and H2SO4 was 4:1:4:4, and the volume ratio of glycerol
to ethanol was 2:1. The mechanical properties of nano-CaSO4 in linear high-density polyethylene (HDPE) were investigated, and
it was found that a low content (3%) of nano-CaSO4 had
a significant reinforcing effect on the mechanical properties. Nano-CaSO4 (3%) can increase the melt strength by nearly 2 times and
increase the tensile strength and elongation at break by 9.16 and
31.43%, respectively; thus, this method is economical and applicable
for the comprehensive utilization of PG.
“…In recent years, the synthesis of CaSO 4 •0.5H 2 O whiskers with high aspect ratios has drawn much attention since they have the greater intensity and the higher use value used as the reinforcing materials in many fields such as plastics, lightweight building materials, ceramics and paper making, etc [1]. To obtain high aspect ratios CaSO 4 •0.5H 2 O whiskers, many researchers have studied the factors that govern the precipitation and dissolution of the CaSO 4 •0.5H 2 O such as temperature [2], reaction time [3], organic [4]or inorganic additives [5,6].…”
CaSO4·0.5H2O whiskers were successfully synthesized by hydrothermal process, in which phosphogypsum (PG) was employed as precursors. The effect of the hexadecyltrimethylammonium bromide (CTAB) on the formation of phosphogypsum-based CaSO4·0.5H2O whiskers was investigated in details. Results indicated that the average diameter and length of as-prepared CaSO4·0.5H2O whiskers with rough surface were about 0.15-2.5μm and 10-50 μm, respectively. The added CTAB templates would effectively guided the selective growth of CaSO4·0.5H2O particles which led to formation of whiskers with high aspect ratios.
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