Effect of concentration, particle size and the presence of protective coatings in DRIFT spectra of building materials

Carmona-Quiroga, Paula María; Blanco-Varela, María Teresa; Domingo, C.; Martínez-Ramírez, S.

doi:10.1016/j.vibspec.2009.03.003

Cited by 5 publications

(1 citation statement)

References 17 publications

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“…The sacrificial products are removed together with the paint and they need to be reapplied; the permanent systems are not taken away during the cleaning process and they can withstand several cleaning cycles. Products used to provide an anti-graffiti barrier to stone surfaces are based on waxes [5], polyurethane [6][7][8], polysaccharides [5], silicon-based resins [5,[9][10][11][12][13], and fluorinated polymers [5,8,[14][15][16][17]; recently, organic-inorganic hybrids [18][19][20][21], nanocomposite materials [22][23][24], and fluorosurfactants [25] have been also proposed as anti-graffiti systems.…”

Section: Introductionmentioning

confidence: 99%

Influence of the Distribution of a Spray Paint on the Efficacy of Anti-Graffiti Coatings on a Highly Porous Natural Stone Material

Masieri

Lettieri

2017

Coatings

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Graffiti on facades often has a heavy impact in social and economic terms, particularly when historical and artistic artefacts are affected. To limit the damages to the surfaces, preventive plans are implemented and anti-graffiti coatings are used as a protective measure. In this study, the distribution of a spray paint inside a highly porous stone, with and without anti-graffiti protection, was investigated. Two commercial sacrificial anti-graffiti systems were used and an acrylic-based paint was applied as staining agent. Environmental scanning electron microscopy and energy-dispersive X-ray spectroscopy (EDS) microanalysis were performed to characterise, from the morphological and chemical point of view, the anti-graffiti coatings and the paint. Maps of the main elements were acquired to locate the different products inside the stone. Chemical removers were used to clean the stained surfaces, then the effectiveness of the cleaning was assessed by visual observations and colour measurements, as well as on the basis of percentage of residual stain. The obtained results highlighted that the anti-graffiti efficacy strongly depended on the characteristics of the applied coating. This latter usually acted as a barrier, but good results were obtained only where the stain did not remain as a separate layer, but penetrated the protective coating. Microcracks in the anti-graffiti coating were able to nullify the protective action.

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