Effect of competitive adsorption on the transport of multiple pollutants through a compacted clay liner

Abstract

Leachate transport through municipal solid waste (MSW) landfill liners can be slowed considerably by adsorption. MSW landfill leachate contains a large variety of pollutants at very different concentrations, and there will be competitive adsorption as these pollutants are transported through the landfill’s compacted clay liner (CCL). In this study, we used batch adsorption tests and geotechnical centrifuge modelling to examine how the adsorption of pollutants commonly found in leachate changed under competitive adsorption conditions and how competitive adsorption affected the CCL breakthrough of multiple pollutants. The results showed that the adsorption of the target pollutant on clay decreased by approximately 30% when competing pollutants were added. The speed at which the pollutants were transported through a 2-m-thick CCL increased, and the breakthrough times reduced by up to 24.8%, when the competing pollutants were mixed. Competitive adsorption significantly promoted the CCL breakthrough of pollutants at low concentrations, but it had limited effect on pollutants at high concentrations.

Centrifuge Modeling of Chloride Ions Completely Breakthrough Kaolin Clay Liner

“…With the gradual increase in the number of old-type landfill sites in China, the transport of pollutants in landfills has been concerned widely [1][2][3]. When the monitoring results of pollutants transport cannot be obtained from field tests, the centrifugal model is also an approach to figure out pollution [4]. The primary mechanisms for pollutants transport in porous media include advection, hydrodynamic dispersion (molecular diffusion and mechanical dispersion), and adsorption [5,6], which are usually described by an advectiondispersion equation [5][6][7]:…”