The composites synthesized with three kinds of B 4 C particles mainly consist of TiC, TiB 2 , and the alloy austenite containing Ni element. Ceramic particulate sizes in the composites synthesized with B3.5 and B45 mm B 4 C particles are larger than that synthesized with B140 mm B 4 C particle. No pores are found between the reinforcing region and matrix in the composites synthesized with B3.5 and B45 mm B 4 C particles, while some large pores exist in the composites synthesized with B140 mm B 4 C particle. With the decrease of B 4 C particle size, the pores in the composites become fewer and the hardness and wear resistance of the composites increase.