Carbon-modified titania (C-TiO 2 ) films were easily prepared by using an impregnation process with a glucose-containing TiO 2 sol. Through controlling calcination conditions, the as-obtained C-TiO 2 products exhibited highly photocatalytic activity for the degradation of gaseous NO x under visible light and ultraviolet illumination. The effects of carbon content and calcination temperature on the photocatalytic performances and their photochemical and physical properties were investigated. Carbonaceous species on the TiO 2 surface enhanced the visible-light absorption of TiO 2 films; however, an excessive amount of carbon on the TiO 2 surface reduced its photocatalytic ability due to the serious coverage effect on active sites. The results show that a suitable glucose addition is about 50-100% of the weight of TiO 2 content and the optimized calcination temperature is 300 • C, which leads to better photocatalytic activity under ultraviolet and visible-light irradiations. Accordingly, the simple-prepared C-TiO 2 films functioned as visible-light-responsive catalysts, allowing for a feasible producing route for real applications.