Effect of boron–carbon–nitride as a negative additive for lead acid batteries operating under high-rate partial-state-of-charge conditions

Kumar, Sudhir; Kiran, Uday Venkat; Arockiakumar, R.; Ambalavanan, S.; Mayavan, Sundar

doi:10.1039/c6ra13458k

Cited by 13 publications

(4 citation statements)

References 17 publications

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“…In the HRPSoC cycling, the researchers found that BCN-NAM exhibited a gradual reduction in its discharge capacity for a cycling test performed with 22 804 cycles in eight consecutive paths. This experimental analysis shows the productive influence of BCN in LABs . From the given analysis, it is clear that BCN-based materials have prominent applications in lead-based metal-ion batteries, but an in-depth analysis regarding the utilization of their features is necessary to accomplish this.…”

Section: Applications Of Boron Carbon Nitride In Rechargeable Batteriesmentioning

confidence: 83%

Boron Carbon Nitride (BCN): An Emerging Two-Dimensional Material for Rechargeable Batteries

Thomas,

Cherusseri,

Pallavolu

et al. 2024

Energy Fuels

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Boron carbon nitride (BCN) is a prominent ultrathin two-dimensional (2D) material that has received significant attention in the recent past. BCN possesses unique properties such as good electronic conductivity, layered 2D architecture, large surface area, good chemical and electrochemical stabilities, etc. Rechargeable batteries, such as lithiumion batteries (LIBs), have made a technological revolution in the field of electrochemical energy storage devices. Electrode materials with layered 2D architectures are highly preferred for application in rechargeable batteries. BCN-based electrodes are potential candidates for rechargeable battery applications and have motivated us to write this review on BCN as an emerging electrode material for applications in batteries. This review discusses the potential of BCN-based materials for rechargeable battery applications and the lack of these materials in the literature. Initially, we discuss the crystal structure of BCN. Further, the various available methods to synthesize BCN nanostructures such as hydrothermal methods, chemical vapor deposition, and pyrolysis, to name a few, are discussed. Additionally, the electrode applications of BCN-based materials for LIBs, Zn−air batteries, Li−O 2 batteries, Li−sulfur batteries, etc., are reviewed in detail. The present review proclaims the development of novel hierarchical layered 2D BCN-based materials for potential applications in next-generation rechargeable batteries. In addition, it emphasizes the difficulties and potential uses of BCN energy storage systems in the future.

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Section: Applications Of Boron Carbon Nitride In Rechargeable Batteriesmentioning

confidence: 83%

Boron Carbon Nitride (BCN): An Emerging Two-Dimensional Material for Rechargeable Batteries

Thomas,

Cherusseri,

Pallavolu

et al. 2024

Energy Fuels

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“…The carbon in NAM increases the electroactive surface area of an electrode, thereby increasing the conductivity of NAM, physically restrict the growth of lead sulfate crystals, and improves the capacitance of the NAM . Apart from carbon, additives like titanium dioxide, bismuth sulfide, boron carbon nitride, were explored by various researchers as a potential NAM additive for LAB …”

Section: Introductionmentioning

confidence: 99%

Study of Molybdenum Disulfide as a Negative Electrode Additive for Stationary Flooded Lead Acid Batteries with Tubular Positive Plates

et al. 2020

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Two dimensional layered molybdenum disulfide (MoS2) nanosheets possess great potential for lithium‐ion batteries, but their role in lead‐acid batteries (LAB) is not well known and documented. In this work, for the first time, full scale tubular positive flooded lead‐acid battery containing MoS2 in negative electrode was compared to control battery containing only carbon black for stationary/float application. Discharge capacity and an endurance test for 2000 h under constant current charging regime were investigated as per the Indian standard for testing stationary LAB (with tubular positive plate) in monobloc container (IS 13369 : 1992, reaffirmed in 2017). Inclusion of MoS2 does not negatively impact discharge capacity or endurance performance; instead, it improves these parameters 2–5 % over control battery. A significant drop in charging voltage is observed in the battery containing MoS2 throughout 2000 h of endurance testing. A battery containing MoS2 passes a similar current of 15 A at 15.2 V as control battery at 15.8 V. Battery containing MoS2, therefore, could be recharged at lower voltages than control batteries to reach identical Ah, thus delaying the onset of common failure mechanism, i. e., grid corrosion associated with high charging voltages.

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“…Intensive works have mainly focused on the combination with heteroatoms (N and B) [19][20][21][22] or metal species [23][24][25][26][27][28][29][30][31][32] to elevate the HER overpotential on the carbon materials. 33 For example, Bi 2 O 2 CO 3 /AC has gained considerable attention since its excellent cycling performance and strong interaction as a negative additive for LABs.…”

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confidence: 99%

Pb₃(OH)₂(CO₃)₂-Acetylene Black Composites for Enhanced Hydrogen Evolution Reaction Inhibition of Lead-Acid Batteries

Hu¹,

Yang²,

Lai³

et al. 2022

J. Electrochem. Soc.

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Pb3(OH)2(CO3)2-acetylene black (BLC/AB) composite is successfully prepared by a simple and economical sonochemical method and employed as a negative additive for lead-acid batteries (LABs). The electrochemical measurements show that the obtained BLC/AB electrodes have a higher hydrogen evolution reaction (HER) overpotential compared to AB electrode. BLC/AB-2 and BLC/AB-4 battery deliver the excellent rate performance at 1 C rate. What’s more, acetylene black as nucleation centers of Pb3(OH)2(CO3)2 may considerably alleviate irreversible sulfation phenomenon of negative plate, thus enhancing the conductivity and extending the cycle life. Interestingly, the cycle life (1172) of BLC/AB-2 battery is 1.44 times that of the same amount of AB battery (814) at 1C rate. Therefore, the BLC/AB composite is a promising negative additive of LABs.

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Effect of boron–carbon–nitride as a negative additive for lead acid batteries operating under high-rate partial-state-of-charge conditions

Abstract: For BCN-NAM, under HRPSoC cycling conditions, the dominating elementary process is the formation of PbO instead of PbSO4.

Cited by 13 publications

References 17 publications

Boron Carbon Nitride (BCN): An Emerging Two-Dimensional Material for Rechargeable Batteries

Boron Carbon Nitride (BCN): An Emerging Two-Dimensional Material for Rechargeable Batteries

Study of Molybdenum Disulfide as a Negative Electrode Additive for Stationary Flooded Lead Acid Batteries with Tubular Positive Plates

Pb₃(OH)₂(CO₃)₂-Acetylene Black Composites for Enhanced Hydrogen Evolution Reaction Inhibition of Lead-Acid Batteries

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Effect of boron–carbon–nitride as a negative additive for lead acid batteries operating under high-rate partial-state-of-charge conditions

Abstract: For BCN-NAM, under HRPSoC cycling conditions, the dominating elementary process is the formation of PbO instead of PbSO4.

Cited by 13 publications

References 17 publications

Boron Carbon Nitride (BCN): An Emerging Two-Dimensional Material for Rechargeable Batteries

Boron Carbon Nitride (BCN): An Emerging Two-Dimensional Material for Rechargeable Batteries

Study of Molybdenum Disulfide as a Negative Electrode Additive for Stationary Flooded Lead Acid Batteries with Tubular Positive Plates

Pb3(OH)2(CO3)2-Acetylene Black Composites for Enhanced Hydrogen Evolution Reaction Inhibition of Lead-Acid Batteries

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Pb₃(OH)₂(CO₃)₂-Acetylene Black Composites for Enhanced Hydrogen Evolution Reaction Inhibition of Lead-Acid Batteries