An efficient method for the generation of tunable cylindrical vector vortex beams is proposed and demonstrated experimentally using an optically active (OA) material. The uniqueness of the proposed methodology lies in the control over the tunability of the cylindrical vector vortex beams using different concentrations of the optically active material. The efficiency of the generated beams is enhanced by using a single low oblique incidence angle of the input beam on a spatial light modulator with a single-phase profile. Two global parameters are measured experimentally to show the quantitative tunability and efficiency of the generated beams. The proposed method can find applications in the fabrication of various kinds of spiral nanostructures.