Effect of Basicity on Electroreduction with Controlled Oxygen Flow of Molten Slag Containing FeO

Abstract

This paper reports on electroreduction with controlled oxygen flow (COF) for extraction of iron along with oxygen by-product from molten slags containing iron oxide at 1723 K. An electrolytic cell with COF was constructed by an iridium wire cathode and a porous platinum anode sintered on a one-end-closed magnesia-stabilized zirconia-based solid electrolyte tube. Effect of basicity of SiO 2 -CaO-Al 2 O 3 -MgO-FeO slag on electroreduction behavior of FeO was investigated by means of the linear sweep and the potentiostatic electrolysis. The possibility of the zirconia membrane as conductive noncorrosive anode material was also discussed. The results indicate that both cathode alloying and increasing slag basicity are helpful to the FeO electrolytic reduction in the molten slag. With the iridium wire as a cathode and an applied voltage at 2.5 V, higher slag basicity results in higher electrolysis rate and higher reduction ratio of the FeO; however, silicon is also precipitated during electrolysis. The applied voltage can cause the increased porosity in the zirconia membrane. The corrosion of the molten slag to the zirconia membrane during electrolysis is evidently aggravated when the slag basicity reaches 0.8. In order to minimize the corrosion of the molten slag to the zirconia membrane during electrolysis, the slag basicity of 0.6 is relatively advisable for extraction of iron under conditions of experimentation.

Ultra‐High Temperature Molten Oxide Electrochemistry

“…Based on the breakthrough of excellent inert anodes, UTE will provide a feasible and convenient technology to directly produce oxygen from abundant lunar soil on the Moon. [123,124] For the industrial application of UTE, a low-carbon process for metal exaction can be designed and would contribute to the achievement of carbon neutrality. [125,126] Importantly, the entire process-ore pretreatment, energy supply, UTE, product collection, tailings utilization, etc.must be designed and optimized considering the cost, circular economy, and carbon footprint.…”

“…Stable inert anodes with low cost are still the challenge due to the extreme corrosion conditions, such as ultra‐high temperature, and electrochemical and chemical corrosion, etc. Based on the breakthrough of excellent inert anodes, UTE will provide a feasible and convenient technology to directly produce oxygen from abundant lunar soil on the Moon [123, 124] …”

Clean Metals Production by Solid Oxide Membrane Electrolysis Process

“…Our work on aluminum production has shown that adding a high-optical basicity oxide (CaO) to the flux significantly improves the stability of the YSZ membrane. Gao et al have also recently reported a correlation between the optical basicity of the molten salts and the pore formation within YSZ membrane [70]. To completely understand the interaction between each molten flux mixture and the YSZ membrane especially in electrolysis mode, it still requires more detailed investigations from both experimental and theoretical perspectives in the future.…”