Effect of BaO on the structure and properties of bismuth-based low-melting glasses

Abstract

The effect of BaO on the structure and properties of bismuth-based low-melting sealing glasseswere investigated by FTIR, 27 Al NMR and DSC. The results showed that when BaO content was less than or equal to 3 wt-%, BaO provided (O 2-) free oxide ions, which made [AlO 6 ] transform into [AlO 4 ] and made [BO 3 ] transform into [BO 4 ]. The increase of [AlO 4 ] and [BO 4 ] enhanced the network structure and decreased the thermal expansion coefficient of glass-ceramic. But when BaO was more than 3 wt-%, a large amount of Ba 2+ , considered as an external body of network, entered the gap of glass network and weakened the existing bridge oxygen vibration in the glass structure and increased the thermal expansion coefficient. Besides, the crystallisation ability of glasses would be promoted by increasing the heat treatment temperature or the BaO content. The formation of BaAl 2 Si 2 O 8 crystal would improve the acidity resistance of the glass-ceramic to a certain extent.

Tuning the thermal and insulation properties of bismuth borate glass for SiC power electronics packaging

“…Alkaline earth oxides like SrO exhibit favorable effects on modulating the sealing performance of the bismuth‐based glass 20 . The influence of BaO on the structure and properties of bismuth‐based low‐melting point glass, revealed that Ba 2+ can enter the gaps of the glass network, weakening existing bridging oxygen (BO) structures and reducing the softening temperature 22 . For practical SiC applications, not only the encapsulating temperature but also the mechanical properties of glass should be adjusted 23,24 .…”