Effect of B2O3 on the crystallization, structure and properties of MgO–Al2O3–SiO2 glass-ceramics

Luo, Wei; Zhang, Bao; Jiang, Weihui; Liu, Jianmin; Feng, Guo; Xu, Yanqiao; Tang, Huidong; Wang, Tao

doi:10.1016/j.ceramint.2019.08.215

Cited by 61 publications

(16 citation statements)

References 24 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…In the range of 400 to 600 cm -1 , the vibration absorption peak at 470 cm -1 was divided into two absorption peaks: 472 cm -1 and 424 cm -1 . The peak at 472 cm -1 was attributed to the bending vibration of Si-O-Si in the residual glass phase and diopside phase (a small amount of hyalophane), the peak at 424 cm -1 was attributed to the bending vibration of Si-O-Al bond in gehlenite [24,30]. There were two vibration absorption peaks at 544 cm -1 and 579 cm -1 , which were not found in the base glass in Figure 4.…”

Section: Ftir Analysismentioning

confidence: 94%

“…There were two vibration absorption peaks at 544 cm -1 and 579 cm -1 , which were not found in the base glass in Figure 4. This was due to the coupling effect between the bending vibration of O-Si-O in the crystal phase and the stretching vibration of Ca-O [24,27]. In the range of 600 to 800 cm -1 , in addition to the vibration absorption peak near 714 cm -1 (base glasses also had the same vibration absorption peak), two new vibration absorption peaks appeared at 682 cm -1 and 630 cm -1 .…”

Section: Ftir Analysismentioning

confidence: 96%

“…In the infrared vibration spectra of glass, the vibration absorption band in the range of 400 to 600 cm -1 was attributed to the bending vibration of Si-O-Si, Si-O-Al, O-Si-O and O-Al-O [23,24].…”

Section: Ftir Analysismentioning

confidence: 99%

See 2 more Smart Citations

STRUCTURE AND PROPERTIES OF GLASS-CERAMICS FROM BLAST FURNACE SLAG WITH DIFFERENT A l₂O₃/S iO₂ RATIO

Li¹

2021

Ceramics - Silikaty

View full text Add to dashboard Cite

Different Al 2 O 3 /SiO 2 glass-ceramics were prepared from blast furnace slag by sintering method. The structure and properties of glasses or glass-ceramics were investigated by DSC, XRD, SEM, FTIR, 27 Al MAS NMR. The DSC results showed that with the increase of Al 2 O 3 /SiO 2 , the glass transition temperature (T g ) first decreased and then increased, reached the minimum when Al 2 O 3 /SiO 2 was 0.34. The volume density, bending strength and microhardness of glass-ceramics also showed the same variation rule. Structural analysis showed that when the Al 2 O 3 /SiO 2 increased from 0.19 to 0.34, Q 2 gradually transformed into Q 1 and Q 3 ; when the Al 2 O 3 /SiO 2 continued to increase from 0.34 to 0.39, Q 1 and Q 3 decreased while Q 2 increased. The variation of [AlO 4 ] and [AlO 6 ] made the glass network structure the loosest when Al 2 O 3 /SiO 2 was 0.34. Gehlenite was the main crystalline phase in glass-ceramics, and with the increase of Al 2 O 3 /SiO 2 , the precipitation of gehlenite increased, while the precipitation of diopside and hyalophane decreased.

show abstract

Section: Ftir Analysismentioning

confidence: 94%

Section: Ftir Analysismentioning

confidence: 96%

See 1 more Smart Citation

STRUCTURE AND PROPERTIES OF GLASS-CERAMICS FROM BLAST FURNACE SLAG WITH DIFFERENT A l₂O₃/S iO₂ RATIO

Li¹

2021

Ceramics - Silikaty

View full text Add to dashboard Cite

show abstract

“…4. This was due to the coupling effect between the bending vibration of O-Si-O in the crystal phase and the stretching vibration of Ca-O [24,27]. In the range of 600-800 cm − 1 , in addition to the vibration absorption peak near 714 cm − 1 (base glasses also had the same vibration absorption peak), two new vibration absorption peaks appeared at 682 cm − 1 and 630 cm − 1 .…”

Section: Ftir Analysismentioning

confidence: 97%

“…In the range of 400-600cm − 1 , the vibration absorption peak at 470 cm − 1 was divided into two absorption peaks: 472 cm − 1 and 424 cm − 1 . The peak at 472 cm − 1 was attributed to the bending vibration of Si-O-Si in the residual glass phase and diopside phase (a small amount of hyalophane), the peak at 424 cm − 1 was attributed to the bending vibration of Si-O-Al bond in gehlenite [24,30]. The intensity of the vibration absorption peak at 424 cm − 1 gradually increased for A1-A5, which indicated that the content of gehlenite increased in glass ceramics with the increase of Al 2 O 3 /SiO 2 .…”

Section: Ftir Analysismentioning

confidence: 99%

Effect of Al2O3/SiO2 on the structure and properties of blast furnace slag glass-ceramics

Zhang

et al. 2020

Preprint

View full text Add to dashboard Cite

Different Al2O3/SiO2 glass-ceramics were prepared from blast furnace slag by traditional sintering method. The structure and properties of glasses or glass-ceramics were investigated by DSC, XRD, SEM, FTIR, 27Al MAS NMR. The DSC results showed that with the increase of Al2O3/SiO2, the glass transition temperature (Tg) first increased and then decreased, reached the minimum when Al2O3/SiO2 was 0.34. The volume density, bending strength and microhardness of glass-ceramics also showed the same variation rule. The FTIR and 27Al MAS NMR spectra results revealed this phenomenon. When Al2O3/SiO2 was 0.19, a large amount of Si4+ was added to the glass network to make the structure dense. With Al2O3/SiO2 increased from 0.24 to 0.34, the amount of [AlO6] in the glass increased while [AlO4] decreased, and the degree of network polymerization of the glass decreased; as Al2O3/SiO2 further increased from 0.34 to 0.39, [AlO4] increased and [AlO6] decreased in the glass, and the degree of network polymerization of the glass increased. The XRD results showed that the crystal phase of the glass-ceramics was composed of gehlenite, diopside and hyalophane. Moreover, with the increase of Al2O3/SiO2, the gehlenite content in the glass-ceramics increased, while the content of diopside and hyalophane decreased.

show abstract

The Crystallization, Microstructure, and Dielectric Characteristics of MgO–Al₂O₃–SiO₂–TiO₂–CeO₂ Materials for Microwave Applications

Liao,

Su,

Tan

et al. 2023

Physica Status Solidi (a)

View full text Add to dashboard Cite

In this paper, we investigated the impacts of varying CeO2 contents and heat‐treatment procedures on the crystallization, and microstructure, and dielectric characteristics of MgO‐Al2O3‐SiO2‐TiO2‐CeO2 (MASTC) materials. The research indicated that perrierite, and rutile, and α‐cordierite were the major crystalline phases in the materials. An increased CeO2 content promoted the formation of perrierite and inhibited the precipitation of α‐cordierite and rutile in the glass‐ceramics. An appropriate amount of CeO2 content contributed to a dense microstructure and improved the dielectric characteristics of the samples. However, an excessive amount of CeO2 deteriorated the densification and dielectric characteristics of the MASTC materials. Furthermore, heat‐treatment temperature and duration also had a significant impacts on the crystallization, microstructure, and dielectric performance of the materials. The MASTC material with 20.2 wt% CeO2, heat‐treated at 1100 oC for a duration of 3 h possessed superior characteristics with a density of 3.14 g/cm3, a permittivity of 11.1, and a Q×f factor of 17357 (14 GHz).This article is protected by copyright. All rights reserved.

show abstract

Effect of B2O3 on the crystallization, structure and properties of MgO–Al2O3–SiO2 glass-ceramics

Cited by 61 publications

References 24 publications

STRUCTURE AND PROPERTIES OF GLASS-CERAMICS FROM BLAST FURNACE SLAG WITH DIFFERENT A l₂O₃/S iO₂ RATIO

STRUCTURE AND PROPERTIES OF GLASS-CERAMICS FROM BLAST FURNACE SLAG WITH DIFFERENT A l₂O₃/S iO₂ RATIO

Effect of Al2O3/SiO2 on the structure and properties of blast furnace slag glass-ceramics

The Crystallization, Microstructure, and Dielectric Characteristics of MgO–Al₂O₃–SiO₂–TiO₂–CeO₂ Materials for Microwave Applications

Contact Info

Product

Resources

About

Effect of B2O3 on the crystallization, structure and properties of MgO–Al2O3–SiO2 glass-ceramics

Cited by 61 publications

References 24 publications

STRUCTURE AND PROPERTIES OF GLASS-CERAMICS FROM BLAST FURNACE SLAG WITH DIFFERENT A l₂O₃/S iO₂ RATIO

STRUCTURE AND PROPERTIES OF GLASS-CERAMICS FROM BLAST FURNACE SLAG WITH DIFFERENT A l₂O₃/S iO₂ RATIO

Effect of Al2O3/SiO2 on the structure and properties of blast furnace slag glass-ceramics

The Crystallization, Microstructure, and Dielectric Characteristics of MgO–Al2O3–SiO2–TiO2–CeO2 Materials for Microwave Applications

Contact Info

Product

Resources

About

The Crystallization, Microstructure, and Dielectric Characteristics of MgO–Al₂O₃–SiO₂–TiO₂–CeO₂ Materials for Microwave Applications