2009
DOI: 10.1029/2008jb005884
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Effect of aqueous and carbonic fluids on the dislocation creep strength of quartz

Abstract: [1] Dislocation creep experiments conducted on quartzite indicate that the presence of CO 2 can cause strengthening or weakening depending on the oxygen fugacity ( f O 2 ) of the deformation environment. Under oxidizing conditions (ferrosilite-hematite-quartz), the presence of CO 2 reduces the water fugacity ( f H 2 O ) and results in strengthening of the quartz. Under moderately reducing conditions ($Ni-NiO), CO 2 reacts with H 2 from the sample assembly to form graphite; the water produced by this reaction c… Show more

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Cited by 62 publications
(71 citation statements)
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“…The effects of water on dislocation creep of quartz, including the nucleation, glide, climb and recovery of dislocations, and recrystallization are well known from (1) experimental studies of natural crystals, in which water was introduced into grain interiors (e.g., Griggs, 1967;Blacic, 1975Blacic, , 1981FitzGerald et al, 1991), (2) studies of synthetic and natural quartz varieties with large initial water contents (e.g., Griggs and Blacic, 1965;Hobbs, 1968;Baeta and Ashby, 1970;Kekulawala et al, 1978;Kirby and McCormick, 1979;McLaren et al, 1983;Linker et al, 1984;Gerretsen et al, 1989;Muto et al, 2011;Holyoke and Kronenberg, 2013;Stünitz et al, 2017), and (3) quartzites and polycrystalline quartz aggregates with water added or removed before or during experiments (e.g., Jaoul et al, 1984;Kronenberg and Tullis, 1984;Tullis and Yund, 1989;Hirth and Tullis, 1992;Gleason and Tullis, 1995;Post et al, 1996;Chernak et al, 2009). IR spectroscopy has played a key role in experimental studies of water weakening, through the characterization and measurement of OH absorption bands due to different hydrogen defects and forms of molecular water within quartz interiors (e.g., Kats, 1962;Griggs and Blacic, 1965;Stipp et al, 2006).…”
Section: Introductionmentioning
confidence: 99%
“…The effects of water on dislocation creep of quartz, including the nucleation, glide, climb and recovery of dislocations, and recrystallization are well known from (1) experimental studies of natural crystals, in which water was introduced into grain interiors (e.g., Griggs, 1967;Blacic, 1975Blacic, , 1981FitzGerald et al, 1991), (2) studies of synthetic and natural quartz varieties with large initial water contents (e.g., Griggs and Blacic, 1965;Hobbs, 1968;Baeta and Ashby, 1970;Kekulawala et al, 1978;Kirby and McCormick, 1979;McLaren et al, 1983;Linker et al, 1984;Gerretsen et al, 1989;Muto et al, 2011;Holyoke and Kronenberg, 2013;Stünitz et al, 2017), and (3) quartzites and polycrystalline quartz aggregates with water added or removed before or during experiments (e.g., Jaoul et al, 1984;Kronenberg and Tullis, 1984;Tullis and Yund, 1989;Hirth and Tullis, 1992;Gleason and Tullis, 1995;Post et al, 1996;Chernak et al, 2009). IR spectroscopy has played a key role in experimental studies of water weakening, through the characterization and measurement of OH absorption bands due to different hydrogen defects and forms of molecular water within quartz interiors (e.g., Kats, 1962;Griggs and Blacic, 1965;Stipp et al, 2006).…”
Section: Introductionmentioning
confidence: 99%
“…The water surrounded and penetrated the sample during the deformation experiment. The construction of the assembly is based on Chernak et al (2009). The assembly is shown in Fig.…”
Section: Methodsmentioning
confidence: 99%
“…As for the effects of supplied water on rock deformation, several deformation experiments have been conducted on the addition of water into quartz and feldspar as major constituents of the crust (Kronenberg and Tullis 1984;Den Brok and Spiers 1991;Den Brok et al 1994;Post et al 1996;Post and Tullis 1998;Stünitz et al 2003;Vernooij et al 2006;Chernak et al 2009). These studies revealed that added water reduces the strengths of samples via the enhancement of dislocation creep, diffusion creep, reaction creep, and/or solution-precipitation creep, which are also associated with the development of microstructures.…”
Section: Introductionmentioning
confidence: 99%
“…Assuming equilibrium relationships between dissolved 'water' in the crystal and the surrounding vapor phase, Paterson (1989) derived m values of 1 to 2 for quartz. High-PT experiments with quartz suggested that m ≤ 1 (Chernak et al 2009). Under experimental conditions at temperatures higher than 900°C, water is in a vapor phase and f H 2 O is nearly equal to water pressure.…”
Section: Figurementioning
confidence: 99%