Effect of Apical Ligands, Substituents and Oxidation States on the Electronic Structure of Co(III) Corrolates
Nicolás I. Neuman
Abstract:Cobalt(III) corroles are the most commonly studied types of metallocorroles, yet the details of their electronic structure, ground spin states and place of redox events are not always straightforward. Corroles are redox active, potentially non‐innocent ligands, and it has been found through various experimental and computational techniques, that the innocent or non‐innocent behavior is modulated by the apical ligands bound to the cobalt center. In this work, we aim to analyze the effect of corrole substituents… Show more
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