Abstract:The excellent high temperature performances of isotactic polybutene-1 (iPB-1) in form I are demanded by many thermoplastic products like hot water pipes. However, as iPB-1 melt is a strong liquid...
“…Eqn (3) can further be rewritten as eqn (4).With T ∞ f = 127 °C, = 759 K (ref. 80) and the glass transition temperatures T g s of iPB-1 in the iPB-1/PE4012 blends with various PE4012 weight proportions determined by DSC measurements (Fig. 9), by linearly fitting the plots (Fig.…”
Blending with UHMWPE inhibits the overall melt crystallization kinetics of iPB-1 due to its spherulite nucleation density decrease in spite of the observed spherulite growth enhancement. It may provide a model system for II–I transition study.
“…Eqn (3) can further be rewritten as eqn (4).With T ∞ f = 127 °C, = 759 K (ref. 80) and the glass transition temperatures T g s of iPB-1 in the iPB-1/PE4012 blends with various PE4012 weight proportions determined by DSC measurements (Fig. 9), by linearly fitting the plots (Fig.…”
Blending with UHMWPE inhibits the overall melt crystallization kinetics of iPB-1 due to its spherulite nucleation density decrease in spite of the observed spherulite growth enhancement. It may provide a model system for II–I transition study.
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