Effect of alkali treatment on adhesion of thermoplastic polyurethane elastomer/polyester inter-ply hybrid composites

Abstract

Purpose The purpose of this paper is to investigate the effects of alkali treatment on adhesion of industrial thermoplastic polyurethane elastomer (TPU)/polyester woven fabric inter-ply hybrid composites. Design/methodology/approach Inter-ply hybrid composites were exposed to varying concentration of sodium hydroxide at different temperature and time and their mechanical properties including differential scanning calorimetry, scanning electron microscope, tensile and peeling strength evaluated to determine optimal treatment parameters. Findings Modified polyester fabrics treated with alkali had higher tensile and peeling strengths. Accordingly, alkali treatment roughened the surface of polyester fabric, decreasing warp and weft densities, thus increasing fiber surface energy. The fabric had the highest peeling strength of 3.23 N/mm at treatment of 25% concentration of sodium hydroxide (NaOH). Short-term exposure to ultraviolet had little effect on interfacial adhesion of alkali-treated conveyor belt. Research limitations/implications Polyester fabric, applied in reinforcing industrial conveyor belts, is never degreased, roughened, sensitized or activated. In this paper, one-step treatment of polyester fabric was performed to increase its adhesion with polyester inter-ply hybrid composites, providing a reference for practical industrial application. Practical implications The method developed in this research is simple and provides a solution to improving the interfacial adhesion of TPU/polyester conveyor belt. Originality/value The novel alkali treatment technology has many applications in the interfacial performance of composite materials.

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Study on properties of polyurethane elastomers prepared with different hard segment structure

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