“…The occurrence of intergranular failure in AA6XXX alloys [3,4,37,43,51,52,55], which was also present in nearly all fatigue crack initiation sites in this study, calls for some discussion of the nature of grain boundaries. The presence of grain boundary failure in aluminum alloys is generally attributed to precipitate free zones (PFZ) [3,4,43,51,52] but segregation of impurities to grain boundaries [56], the existence of high angle grain boundaries [57] or large slip gradients across grains [7,8,11,53] could also lead to failure at boundaries in polycrystalline materials. A schematic illustration of a PFZ at a grain boundary triple junction is shown in Figure 2-5.…”