2003
DOI: 10.1002/app.13382
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Effect of a natural magnesium silicate treated with a new coupling agent on the properties of ethylene–propylene–diene rubber compounds

Abstract: ABSTRACT:The behavior of sepiolite (magnesium silicate with a microfibrillar morphology) as a filler in ethylenepropylene-diene compounds was studied. A new coupling agent, meta-isopropenyl dimethyl benzyl isocyanate, was used. The effect of the filler modified by meta-isopropenyl dimethyl benzyl isocyanate on the physical properties was improved with respect to other fillers and commercial silane coupling agents under the same conditions. In addition to a smoother surface, the flow behavior of compounds fille… Show more

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Cited by 7 publications
(3 citation statements)
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“…Previous research [ 32 , 36 , 37 ] has primarily focused on melt mixing, and there is limited information on in situ modification of sepiolite for latex compounding. In this study, we selected three silane coupling agents with different functional groups (see Table 1 ) to modify sepiolite.…”
Section: Introductionmentioning
confidence: 99%
“…Previous research [ 32 , 36 , 37 ] has primarily focused on melt mixing, and there is limited information on in situ modification of sepiolite for latex compounding. In this study, we selected three silane coupling agents with different functional groups (see Table 1 ) to modify sepiolite.…”
Section: Introductionmentioning
confidence: 99%
“…Basically they can be divided in two groups based on either the enhancement of physical adsorption of organic molecules on the silica surface, or on the creation of chemical linkages between polymer chains and the silica surface via coupling agent molecules. [9][10][11] In this context, the synthesis of polymer-silica particles with core-shell, hairy-, multipod-or dumbbell-like morphologies is a step forward in the compatibilization of highly polar silica surfaces and nonpolar polymers. [12][13][14] Moreover, synthesis of these particles in smaller sizes offers various advantages due to the increased specic surface area.…”
Section: Introductionmentioning
confidence: 99%
“…This improvement in the processing behavior is due to the orientation of the fibrilar particles of the silsep in the flow direction. 21 Table IV shows the values obtained for the physical properties of the compounds. As it was expected, the presence of the filler produces an increase in Shore A hardness and in the stress values at low Figure 2 Variation of apparent viscosity with shear rate on capillary flow.…”
mentioning
confidence: 98%