Volume Holographic Optical Elements (vHOEs) provide superior optical properties over DOEs (surface gratings) due to high diffraction efficiencies in the -1 st order and their excellent Bragg selectivity. Bayer MaterialScience is offering a variety of customized instant-developing photopolymer films to meet requirements for a specific optics design of a phase hologram. For instance, the photopolymer film thickness is an ideal means to adjust the angular and the spectral selectivity while the index modulation can be adopted with the film thickness to achieve a specific required dynamic range. This is especially helpful for transmission type holograms and in multiplex recordings. The selection of different substrates is helpful to achieve the overall optical properties for a targeted application that we support in B2B-focused developments. To provide further guidance on how to record volume holograms in Bayfol® HX, we describe in this paper a new route towards the recording of substrate guided vHOEs by using optimized photopolymer films. Furthermore, we discuss special writing conditions that are suitable to create higher 2 nd harmonic intensities and their useful applications.Due to total internal reflection (TIR) at the photopolymer-air interface in substrate guided vHOEs, hologram recording with those large diffraction angles cannot usually be done with two free-space beams. Edge-lit recording setups are used to circumvent this limitation. However, such setups require bulky recording blocks or liquid bathes and are complex and hard to align. A different approach that we present in this paper is to exploit 2 nd harmonic grating generation in a freespace recording scheme. Those 2 nd harmonic components allow the replay of diffraction angles that are normally only accessible with edge-lit writing configurations. Therefore, this approach significantly simplifies master recordings for vHOEs with edge-lit functionalities, which later can be used in contact copy schemes for mass replication.In this paper, we will discuss and illustrate recording parameters to influence 2 nd harmonic efficiency in optimized photopolymer films and will explain preferred geometries for recording.