Ecotoxicological assessment of biomass-derived furan platform chemicals using aquatic and terrestrial bioassays

Parmaki, Stella; Vasquez, Marlen I.; Patsalou, Maria; Gomes, Rafael F. A.; Simeonov, Svilen P.; Afonso, Carlos A. M.; Koutinas, Michalis

doi:10.1039/d3em00552f

Environ. Sci.: Processes Impacts

2024

DOI: 10.1039/d3em00552f

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Ecotoxicological assessment of biomass-derived furan platform chemicals using aquatic and terrestrial bioassays

Stella Parmaki,

Marlen I. Vasquez,

Maria Patsalou

et al.

Abstract: An environmental toxicological assessment of fourteen furanic compounds serving as valuable building blocks produced from biomass was performed. The molecules selected included well studied compounds serving as control examples to...

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Diels–Alder Cycloaddition of 2,5-Bis(hydroxymethyl)furan (BHMF) and N-Phenylmaleimide Derivatives

Shukla,

Promcharoen,

Poonsawat

et al. 2024

ACS Omega

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Currently, amidst atmospheric menace where natural calamities such as wildfire and floods are becoming more frequent than ever, biobased derivatives offer a sustainable alternative to conventional ways, for instance, petrochemical commodities. Biobased products, obtained from agricultural waste, including 5-(hydroxymethyl)furfural (HMF), 2,5-bis(hydroxymethyl)furan (BHMF), and 2,5-furandicarboxylic acid (FDCA) are promising chemical platforms in the biorefinery, which is yet to be explored. The Diels–Alder cycloaddition of BHMF and N-phenylmaleimide derivatives under optimal reaction conditions is investigated in this report. First, HMF is reduced to BHMF in the presence of NaBH4, and then the Diels–Alder reaction of BHMF and N-phenylmaleimide derivatives is investigated to produce Diels–Alder adducts. All novel compounds are synthesized in acceptable yields and effectively characterized by employing important techniques such as one-dimensional (1D) NMR spectroscopy (1H, 13C, DEPT-90, and DEPT- 135), two-dimensional (2D) NMR spectroscopy (1H–1H COSY, 1H–13C HSQC, and 1H–13C HMBC), IR spectroscopy, elemental analysis, mass spectrum (QTOF), and single-crystal X-ray diffraction (SC-XRD). Furthermore, this study underlines the necessity of sustainable synthetic methodologies and gives critical insights into the progress of ecologically friendly methodologies, providing a new avenue as a tunable precursor for the challenging functionalized polymer in the future.

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Diels–Alder Cycloaddition of 2,5-Bis(hydroxymethyl)furan (BHMF) and N-Phenylmaleimide Derivatives

Shukla,

Promcharoen,

Poonsawat

et al. 2024

ACS Omega

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show abstract

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Ecotoxicological assessment of biomass-derived furan platform chemicals using aquatic and terrestrial bioassays

Abstract: An environmental toxicological assessment of fourteen furanic compounds serving as valuable building blocks produced from biomass was performed. The molecules selected included well studied compounds serving as control examples to...

Cited by 1 publication

References 83 publications

Diels–Alder Cycloaddition of 2,5-Bis(hydroxymethyl)furan (BHMF) and N-Phenylmaleimide Derivatives

Diels–Alder Cycloaddition of 2,5-Bis(hydroxymethyl)furan (BHMF) and N-Phenylmaleimide Derivatives

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