Abstract:Cotton dyeing is usually performed by reactive dyes by exhaustion method. Great quantities of salts and alkalis used in the formulation of dyeing bath eventually get into the watercourses and negatively affect the environment. In this work, studied are the possibilities of reducing salt and alkali concentrations in the dyeing bath in order to reduce water pollution after the dyeing process and soap washing. The obtained results show that the alternative procedures are environmentally more favorable, which is d… Show more
“…The next step is to optimize the surface functionalization techniques to incorporate the desired type and amount of the reactive functional group [19,[21][22][23]. Considering the importance of polyester as a synthetic polymer in this research, before treatment with chitosan, polyester materials can be modified by UV irradiation [23], plasma pretreatment [24,25], enzymatic treatments [26], or alkaline hydrolysis prior to treatment with chitosan to activate the surface and increase the hydrophilicity of the polymer structure [27][28][29][30].…”
Section: Introductionmentioning
confidence: 99%
“…Alkaline hydrolysis of polyester fibers in the alkali is a traditional high-efficiency pretreatment process that takes place on the surface [10,[26][27][28]. Some studies have shown that alkaline hydrolysis can improve the coating of functional polymers to form fine roughness of polyester [12,30].…”
The existing research deals with the process of modifying polyester knitted fabrics and polyester/cotton knitted fabrics with chitosan and the stability of functionalized surface with chitosan in the washing process according to a standard and an innovative washing procedure. The current research concept aims to evaluate the degree of progressivity and progressiveness: the modification of polyester knitted fabrics with chitosan and an innovative washing process. The polyester and polyester/cotton fabrics modified with chitosan were characterized by a staining test, microscopic analysis, zeta potential measurement, and pilling tendency of the knitted fabrics before and after five and ten washing cycles with reference detergent ECE A. The results of the zeta potential measurement of knitted fabrics functionalized with chitosan confirmed cationization of the polyester and polyester/cotton fabric with chitosan. The presence of chitosan on the washed knitted fabrics in reduced quantities is demonstrated by the staining test, the colour strength (K/S), and the zeta potential values. The staining test and surface charge of the tested knitted fabrics confirmed the research hypothesis regarding the degree of progressivity of the modification of polyester and polyester/cotton knitted fabrics with chitosan and the sustainability of the innovative washing process. The streaming potential proved to be a favorable method for monitoring the stability of chitosan in the washing process in combination with a staining test with the selected dye Remazol Red RB.
“…The next step is to optimize the surface functionalization techniques to incorporate the desired type and amount of the reactive functional group [19,[21][22][23]. Considering the importance of polyester as a synthetic polymer in this research, before treatment with chitosan, polyester materials can be modified by UV irradiation [23], plasma pretreatment [24,25], enzymatic treatments [26], or alkaline hydrolysis prior to treatment with chitosan to activate the surface and increase the hydrophilicity of the polymer structure [27][28][29][30].…”
Section: Introductionmentioning
confidence: 99%
“…Alkaline hydrolysis of polyester fibers in the alkali is a traditional high-efficiency pretreatment process that takes place on the surface [10,[26][27][28]. Some studies have shown that alkaline hydrolysis can improve the coating of functional polymers to form fine roughness of polyester [12,30].…”
The existing research deals with the process of modifying polyester knitted fabrics and polyester/cotton knitted fabrics with chitosan and the stability of functionalized surface with chitosan in the washing process according to a standard and an innovative washing procedure. The current research concept aims to evaluate the degree of progressivity and progressiveness: the modification of polyester knitted fabrics with chitosan and an innovative washing process. The polyester and polyester/cotton fabrics modified with chitosan were characterized by a staining test, microscopic analysis, zeta potential measurement, and pilling tendency of the knitted fabrics before and after five and ten washing cycles with reference detergent ECE A. The results of the zeta potential measurement of knitted fabrics functionalized with chitosan confirmed cationization of the polyester and polyester/cotton fabric with chitosan. The presence of chitosan on the washed knitted fabrics in reduced quantities is demonstrated by the staining test, the colour strength (K/S), and the zeta potential values. The staining test and surface charge of the tested knitted fabrics confirmed the research hypothesis regarding the degree of progressivity of the modification of polyester and polyester/cotton knitted fabrics with chitosan and the sustainability of the innovative washing process. The streaming potential proved to be a favorable method for monitoring the stability of chitosan in the washing process in combination with a staining test with the selected dye Remazol Red RB.
“…The reactive dyes have the ability to form covalent bonds with the material fibers through a nucleophilic mechanism [2]. Most dyes are ecologically hazardous [3] and toxic to human health [4]. The human body comes in daily contact under any circumstance with these reactive dyes through clothing, underwear made of cotton.…”
The paper describes the photochemical stability of a commercial triphenodioxazine dye (Reactive Blue_204) linked onto a cotton fabric. Preliminary studies have shown that as a result of irradiation, the dye and its photodegradation products can pass directly onto the skin under conditions that mimic human perspiration and cause side-effects. The cotton dyed fabric was photo irradiated at different time intervals. Standard methods were employed to evaluate the color strength at various levels of pH, temperature, dyeing contact time, and salt concentration. The influence of UV radiation at different doses (λ > 300 nm) on the structural and color modifications of the dyed cotton fabrics was studied. Structural modifications before and after irradiation were compared by applying FTIR, UV–Vis, and near infrared chemical imaging (NIR–CI) techniques. Color modifications were investigated with the CIELAB system. Color differences significantly increased with the irradiation dose. High irradiation doses caused changes in the dye structure.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.