Abstract:Major changes of the environment are caused by the presence of pollutants in air, soil, and wastewaters. From these, a major attention is accorded to the industrial wastewaters, because can contain simultaneous different types of pollutants such as heavy metals, anions, dyes, phenols, pesticides, drugs, etc. For wastewater treatment, consecrated methods such as adsorption, photocatalysis, membrane separation, etc. can be used, adsorption being considered one of the most favorable techniques. In the last years,… Show more
“…This fact was observed when the fly ash was treated with NaOH and H 2 SO 4 [ 15 , 26 ]. Additionally, other researchers have obtained similar results [ 12 , 24 ].…”
Section: Resultssupporting
confidence: 77%
“…Fly ash is preferred as an adsorbent since it is a cheap and highly-available material [ 24 , 25 ]. On the other hand, there are highlights that the presence of fly ash discharged from thermal power plants by the burning of coal represents a big environmental issue [ 26 , 27 , 28 , 29 ].…”
Fly ash/magnetite material was used for the adsorption of copper ions from synthetic wastewater. The obtained material was characterized by scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDAX), X-ray diffractometer (XRD), Fourier transform infrared spectroscopy (FTIR), Brunauer–Emmett–Teller (BET) surface area, and vibrating sample magnetometer (VSM). Batch adsorption experiments were employed in order to investigate the effects of adsorbent dose, initial Cu (II) concentration and contact time over adsorption efficiency. The experimental isotherms were modeled using Langmuir (four types of its linearization), Freundlich, Temkin, and Harkins–Jura isotherm models. The fits of the results are estimated according to the Langmuir isotherm, with a maximum adsorption capacity of 17.39 mg/g. The pseudo-second-order model was able to describe kinetic results. The data obtained throughout the study prove that this novel material represents a potential low-cost adsorbent for copper adsorption with improved adsorption capacity and magnetic separation capability compared with raw fly ash.
“…This fact was observed when the fly ash was treated with NaOH and H 2 SO 4 [ 15 , 26 ]. Additionally, other researchers have obtained similar results [ 12 , 24 ].…”
Section: Resultssupporting
confidence: 77%
“…Fly ash is preferred as an adsorbent since it is a cheap and highly-available material [ 24 , 25 ]. On the other hand, there are highlights that the presence of fly ash discharged from thermal power plants by the burning of coal represents a big environmental issue [ 26 , 27 , 28 , 29 ].…”
Fly ash/magnetite material was used for the adsorption of copper ions from synthetic wastewater. The obtained material was characterized by scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDAX), X-ray diffractometer (XRD), Fourier transform infrared spectroscopy (FTIR), Brunauer–Emmett–Teller (BET) surface area, and vibrating sample magnetometer (VSM). Batch adsorption experiments were employed in order to investigate the effects of adsorbent dose, initial Cu (II) concentration and contact time over adsorption efficiency. The experimental isotherms were modeled using Langmuir (four types of its linearization), Freundlich, Temkin, and Harkins–Jura isotherm models. The fits of the results are estimated according to the Langmuir isotherm, with a maximum adsorption capacity of 17.39 mg/g. The pseudo-second-order model was able to describe kinetic results. The data obtained throughout the study prove that this novel material represents a potential low-cost adsorbent for copper adsorption with improved adsorption capacity and magnetic separation capability compared with raw fly ash.
“…The scientists' concern for the green elimination of various persistent organic contaminants from wastewaters resulted, among others, in a high interest paid for obtaining highly performant materials for the photocatalytic reactions mediated by semiconductive solids, by oxidation reactions [1][2][3][4]. This class of reactions belong to the so-called AOPs (Advanced Oxidation Process), being very popular especially for the purification of wastewaters from low amounts of pesticides, drug compounds, dyes, disinfectants and other very stable and non-biodegradable chemicals, which depreciate the water quality, despite their ppm-range concentrations [5,6].…”
Mixed oxides containing zinc and lanthanum were prepared by coprecipitation in alkaline medium, followed by calcination at 400 °C. The initial precipitation product and the calcined form were characterized by Brunauer–Emmett–Teller (BET) method adsorption of nitrogen at −196 °C, Scanning Electron Microscopy/Electron-Probe Microanalysis (SEM/EPM), Ultraviolet - Diffuse Reflectance Spectroscopy (UV-DRS) and Infrared (IR) spectroscopy. The band gap slightly changes from 3.23 eV to 3 eV by calcination. The photocatalytic performance of the solids were investigated in diluted aqueous medium, by using clofibric acid (CA), a stable and toxic molecule used as precursor in some pesticides and drugs, as test compound, possibly found in the wastewaters in low concentrations. The effects of the degradation extent, determined by high performance liquid chromatography (HPLC) and total organic carbon (TOC) measurements, were investigated at different initial concentrations of CA. Within about 60 min the CA degradation is almost total at low concentration values (3 ppm) and reaches over 80% in 180 min for an initial concentration of 50 ppm. Moreover, the CA removal performance of photocatalyst remains excellent after three cycles of use: the removal yield was practically total after 60 min in the first two cycles and reached 95% even in the third cycle.
“…Pollution with heavy metals (cadmium, copper, nickel, lead, chromium) from different industrial wastewaters represents a serious problem for the environment and human health [ 1 ]. Nanotechnology addresses the continuous development of solutions to the existing environmental problems and preventive measures for future problems.…”
Novel hybrid inorganic CoFe2O4/carboxymethyl cellulose (CMC) polymeric framework nanobeads-type adsorbents with tailored magnetic properties were synthesized by a combination of coprecipitation and flash-cooling technology. Precise self-assembly engineering of their shape and composition combined with deep testing for cadmium removal from wastewater are investigated. The development of a single nanoscale object with controllable composition and spatial arrangement of CoFe2O4 (CF) nanoparticles in carboxymethyl cellulose (CMC) as polymeric matrix, is giving new boosts to treatments of wastewaters containing heavy metals. The magnetic nanobeads were characterized by means of scanning electron microscopy (SEM), powder X-ray diffraction analysis (XRD), thermogravimetric analysis (TG), and vibrational sample magnetometer (VSM). The magnetic properties of CF@CMC sample clearly exhibit ferromagnetic nature. Value of 40.6 emu/g of saturation magnetization would be exploited for magnetic separation from aqueous solution. In the adsorptions experiments the assessment of equilibrium and kinetic parameters were carried out by varying adsorbent dosage, contact time and cadmium ion concentration. The kinetic behavior of adsorption process was best described by pseudo-second-order model and the Langmuir isotherm was fitted best with maximum capacity uptake of 44.05 mg/g.
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