Abstract:Abstract. The ECE (Electrochemical, Chemical, Electrochemical) and DISP (DISProportionation) mechanisms describe electrochemical reactions between four species in a diffusive solution. The general set of reactions which encompass both mechanisms is modelled by:in the case when the applied overpotential is large enough that only the forward steps in (i) and (iii) are present. The ECE mechanism follows the pathway (i), (ii), (iii). The DISP mechanism follows the pathway (i), (ii), (iv). These electrochemical me… Show more
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