2018
DOI: 10.1039/c8dt01562g
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Easily reduced bis-pincer (NS2)2molybdenum(iv) to (NHS2)2Mo(ii) by alcoholsvs. redox-inert (NS2)(NHS2)iron(iii) complexes

Abstract: Iron and molybdenum complexes supported by a pincer-type dianionic [NS2]2- donor were prepared to compare their structural, spectroscopic, and electrochemical properties. The versatility of the [NS2]2Mo(iv) complex (2) to access different oxidation states was evidenced in the activation of methanol and isopropanol, oxidising them to formaldehyde or acetone with concomitant reduction and protonation to afford [NHS2]2Mo(ii), complex (3). This redox behaviour contrasts with the null reactivity observed for the an… Show more

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Cited by 3 publications
(1 citation statement)
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“…The unsubstituted S-2-(chloromethyl)phenyl-N,N-dimethylthiocarbamate and the corresponding ortho-, para-substituted S-2-(chloromethyl-4-methyl-6-(aryl-bis-3,5-trifluoromethyl)phenyl-N,N-dimethylthiocarbamate building blocks used for the synthesis of ligand precursors were formerly obtained according to the previously published method. [23] NMR spectra were acquired using Bruker spectrometers operating at 400 MHz ( 1 H) and 100 MHz ( 13 C). Applying the residual solvent peaks or tetramethylsilane as internal references, chemical shifts are reported in parts per million (TMS δ = 0.00, CHCl 3 δ = 7.26 ppm).…”
Section: Methodsmentioning
confidence: 99%
“…The unsubstituted S-2-(chloromethyl)phenyl-N,N-dimethylthiocarbamate and the corresponding ortho-, para-substituted S-2-(chloromethyl-4-methyl-6-(aryl-bis-3,5-trifluoromethyl)phenyl-N,N-dimethylthiocarbamate building blocks used for the synthesis of ligand precursors were formerly obtained according to the previously published method. [23] NMR spectra were acquired using Bruker spectrometers operating at 400 MHz ( 1 H) and 100 MHz ( 13 C). Applying the residual solvent peaks or tetramethylsilane as internal references, chemical shifts are reported in parts per million (TMS δ = 0.00, CHCl 3 δ = 7.26 ppm).…”
Section: Methodsmentioning
confidence: 99%