Easily Accessible Chiral P,N-Bidentate Aryl Phosphites, Their Complexation and Application in Enantioselective Allylic Alkylation, Sulfonylation and Hydrosilylation
Abstract:New chiral P,N-hybrid aryl phosphites have been obtained by one-step phosphorylation of amino and imino alcohols. Complexation of the new ligands with [Rh(CO) 2 Cl] 2 , [Pd(COD)Cl 2 ] and [Pd(allyl)Cl] 2 was found to give chelate complexes [Rh(CO)Cl(η 2 -P ʝ N)], [PdCl 2 (η 2 -P ʝ N)] and [Pd-(allyl)(η 2 -P ʝ N)] + Cl − , respectively. With these new P,N-ligands, up to 82% ee enantioselectivity was achieved in the [a] The new P,N-bidentate aryl phosphites were synthesized by one-step phosphorylation of the co… Show more
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