“…The most frequently studied geochemical phenomena have been concentrations of dissolved gas and ions in groundwater and variations in concentra-tions of crustal and mantle volatiles in ground gases. (Wakita, 1978;King, 1980;Nakamura and Wakita, 1985;Wakita et al, 1985Wakita et al, , 1986Thomas, 1988;King et al, 1994;Koch and Heinicke, 1994;Dongarra et al, 1995;Heinicke et al, 1995;Igarashi et al, 1995;Shimizu et al, 1996;Monnin and Seidel, 1997;Bella et al, 1998;Di Bello et al, 1998;Woith et al, 1998;Singh et al, 1999;Zhang, 1999;Biagi et al, 2000;Heinicke et al, 2000;Favara et al, 2001;Koch et al, 2003).…”