“…Water drops were systematically added onto aluminaforming CeO 2 based coatings during the cold stage (T b 80°C) of cyclic oxidation [13]. This aimed at simulating repeated condensation of water released by kerosene combustion or relative humidity of air and rain after engine operation.…”
“…Water drops were systematically added onto aluminaforming CeO 2 based coatings during the cold stage (T b 80°C) of cyclic oxidation [13]. This aimed at simulating repeated condensation of water released by kerosene combustion or relative humidity of air and rain after engine operation.…”
“…The perovskites improved the adherence of the oxide scale formed and blocked diffusion of the ionic species, hence resulting in overall improved oxidation resistance [24,25]. In some of our previous studies, the formation of CeAlO3 at the alumina/ceria interface was also considered to contribute to the enhanced adherence of the oxide scale of electrolytic CeO2 coatings on Ni-based superalloy substrates under isothermal and cyclic conditions [26][27][28] even after the application of water drops to embrittle the oxide/coating interface [29,30]. Nevertheless, despite favourable thermodynamic conditions, this was not clearly demonstrated experimentally.…”
Perovskite type phases are known to improve the adherence of protective oxide scales grown onto chromia-and alumina-forming alloys and coatings. The present study investigates the interfacial reactions occurring during the high temperature oxidation of a ceria coated Ni-based superalloy at 1100°C. The substrate firstly grew a duplex oxide scale with a NiAl2O4 spinel on top of an α-Al2O3 scale underneath the ceria coating. Increasing oxidation time led to the development of Al-rich and Ce-rich nanometric grains at the oxide scale/coating interface and to the progressive vanishing of the NiAl2O4 spinel. Micro-Raman analyses demonstrated the formation of cerium aluminate CeAlO3 by solid-state reaction between Al2O3 and CeO2 favoured by an Al supply coming from the substrate. The results are in line with the thermodynamic calculations.
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