“…19 WPCBs are then divided into bare boards and ECs for the deep processing step. 20 In the deep treatment stage, researchers have developed mechanical, 21 pyrogenic, 22 pyrolysis, 23 wet, [24][25][26] bioleaching, [27][28][29] and many other methods for resource recovery of WPCBs. For example, Wang et al 30 proposed a process to recover copper from PCBs by froth otation and oxidative leaching to increase the copper grade from 38.70% to 68.34%.…”
As a key component of all Electrical and Electronic Equipment, Waste Printed Circuit Boards (WPCBs) are an important target for Waste Electrical and Electronic Equipment (WEEE) treatment. Over the years,...
“…19 WPCBs are then divided into bare boards and ECs for the deep processing step. 20 In the deep treatment stage, researchers have developed mechanical, 21 pyrogenic, 22 pyrolysis, 23 wet, [24][25][26] bioleaching, [27][28][29] and many other methods for resource recovery of WPCBs. For example, Wang et al 30 proposed a process to recover copper from PCBs by froth otation and oxidative leaching to increase the copper grade from 38.70% to 68.34%.…”
As a key component of all Electrical and Electronic Equipment, Waste Printed Circuit Boards (WPCBs) are an important target for Waste Electrical and Electronic Equipment (WEEE) treatment. Over the years,...
“…[ 50 ] The fact of having the two elements Pb and Sn also tends to promote oxidation as shown by Equation (13): the presence of tin promotes the oxidation of lead and it is possible to form SnO 2 from SnO via the presence of lead. [ 6 ] As the PbO solubility is high in HCl, the interaction between the two elements improves consequently the formation of cerussite, a bulky and fragile corrosion product. That is why CO 2 is qualified as a contaminant in electronic [ 51 ] and attention is paid to the storage of the Pb–Sn alloy in sliding bearing.…”
Section: Discussionmentioning
confidence: 99%
“…[3,4] Nevertheless, recent research using the Pb-Sn alloy has demonstrated the recycling of valuable Pb and Sn elements from electronic waste. [5][6][7] More generally, the Pb-Sn alloys are used in a lot of domains: Pb-Sb alloy is used as grid materials in lead-acid batteries [8] because of its good casting and deep cycling properties, [9] as shielding materials for highly penetrating radiations of gamma rays during the reactions occurring in nuclear reactors [10] or as a lubricating coating. [11] As it is used in many domains, the Pb-Sn alloy can be exposed to different environments, potentially corrosive.…”
This article synthesizes all the results obtained to establish a global corrosion mechanism when a Pb–Sn coating deposited on low carbon steel is corroded in an HCl‐polluted wet environment. The successive stages of the process are shown. In HCl‐polluted environment, coupled with water, acid chlorides provide an aggressive electrolyte particularly favorable to corrosion. In contact with this electrolyte, lead products are created as PbCO3 and PbCl2, showing the impact of the surrounding atmosphere. In parallel, the electrolyte concentrates in Sn2+ until saturation, and tin precipitates under different forms. Due to the lead consumption, the lead corrosion products layer breaks, and the coating thins, diffusion pathways are created and the steel oxidizes. Iron corrosion products are similar with or without a coating except for the presence of a tin‐rich filament. Lead is no longer present. The different stages of the mechanism are compared to corrosion phenomena observed during the use of Pb–Sn alloys to provide effective solutions to minimize or even avoid the phenomenon of corrosion.
“…So, even if recycling e-waste and reusing their components, with a similar purpose to the original one, remain the preferred approaches, the recovery of all the components is often hindered by the intricate nature of electronic devices [ 5 ]. Extended activities in research and procedure optimization have been performed in this sense, leading to the development of specific recycling chains, after the preliminary steps of dismantling, sorting, and mechanical pretreatment (such as shredding and crushing) [ 6 , 7 , 8 ].…”
Section: Introductionmentioning
confidence: 99%
“…The polymeric components are mainly thermoset resins and reinforcement materials, which can barely be recycled because their crosslinked structure makes their melting impossible using conventional processes. Traditionally, these materials are landfilled or incinerated, but recently their recovery and use as fillers for epoxy or polypropylene resin products, such as paints, adhesives, decorating agents, and building materials, have been proposed [ 8 , 23 , 24 ].…”
Electronic waste (e-waste) is one of the fastest-growing waste streams in the world and Europe is classified as the first producer in terms of per capita amount. To reduce the environmental impact of e-waste, it is important to recycle it. This work shows the possibility of reusing glassy substrates, derived from the MW-assisted acidic leaching of Waste Printed Circuit Boards (WPCBs), as an adsorbent material. The results revealed an excellent adsorption capability against methylene blue (MB; aqueous solutions in the concentration range 10−5 M–2 × 10−5 M, at pH = 7.5). Comparisons were performed with reference samples such as activated carbons (ACs), the adsorbent mostly used at the industrial level; untreated PCB samples; and ground glass slides. The obtained results show that MW-treated WPCB powder outperformed both ground glass and ground untreated PCBs in MB adsorption, almost matching AC adsorption. The use of this new adsorbent obtained through the valorization of e-waste offers advantages not only in terms of cost but also in terms of environmental sustainability.
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