The process of complexification is used to classify a Lie algebra and identify its Cartan subalgebra. However, this method does not distinguish between real forms of a complex Lie algebra, which can differ in signature. In this paper, we show how Cartan decompositions of a complexified Lie algebra can be combined with information from the Killing form to identify real forms of a given Lie algebra. We apply this technique to sl(3, O), a real form of e 6 with signature (52,26), thereby identifying chains of real subalgebras and their corresponding Cartan subalgebras within e 6 . Motivated by an explicit construction of sl(3, O), we then construct an abelian group of order 8 which acts on the real forms of e 6 , leading to the identification of 8 particular copies of the 5 real forms of e 6 , which can be distinguished by their relationship to the original copy of sl(3, O).