Many physical systems are described by partial differential equations (PDEs). Determinism then requires the Cauchy problem to be well-posed. Even when the Cauchy problem is well-posed for generic Cauchy data, there may exist characteristic Cauchy data. Characteristics of PDEs play an important role both in Mathematics and in Physics. I will review the theory of characteristics and bicharacteristics of PDEs, with a special emphasis on intrinsic aspects, i.e. those aspects which are invariant under general changes of coordinates. After a basically analytic introduction, I will pass to a modern, geometric point of view, presenting characteristics within the jet space approach to PDEs. In particular, I will discuss the relationship between characteristics and singularities of solutions and observe that: "wave-fronts are characteristic surfaces and propagate along bicharacteristics". This remark may be understood as a mathematical formulation of the wave/particle duality in optics and/or quantum mechanics. The content of the paper reflects the three-hour mini-course that I gave at the XXII International Fall Workshop on Geometry and Physics, September 2–5, 2013, Évora, Portugal.