Cellulose fiber materials
suitable for filtering, insulation, protective,
and hygiene applications can be formed using aqueous foam as a carrier
phase. The subtle fiber–bubble interaction provides a tool
which can be utilized to alter both structural and mechanical material
properties. Earlier model surface studies have only indicated clear
surface-bubble adhesion when both the surface hydrophobicity and surface
tension of the solution are high enough. In this work, we first show
that for silica model surfaces these basic mechanisms are similar
for both nonionic polyethylene glycol sorbitan monolaurate (Tween
20) and anionic sodium dodecyl sulfate (SDS) surfactants. In the second
step, thick nonwoven materials were foam formed from hydrophilic or
hydrophobic viscose fibers using small amounts of cellulose microfibers
(CMFs) to form a bonding agent. There was a clear variation in structure
and strength properties between the samples made using different fibers
and surfactants. The partial alignment and layering of fibers in the
wet foam led to anisotropy in the mechanical properties of the formed
samples. Using SDS, the fiber alignment was very strong for hydrophilic
fibers but was reduced for hydrophobic fibers because of stronger
coupling to bubbles during structure forming, impacting the microscale
fiber network. For nonionic Tween 20, in addition to surfactant adsorption
on the fibers, the ethoxylated surfactant headgroups are suggested
to form bridges between CMFs and other fibers, restricting fiber movements
during formation. For hydrophilic fibers, this showed up as a lower
in-plane compression modulus but higher transverse strength for Tween
20 compared with SDS surfactant. For hydrophobic fibers, the sensitivity
of the mechanical properties on surfactant type was even stronger.