Spontaneous pattern formation is a phenomenon ubiquitous in nature, examples ranging from Rayleigh-Benard convection to the emergence of complex organisms from a single cell. In physical systems, pattern formation is generally associated with the spontaneous breaking of translation symmetry and is closely related to other symmetry-breaking phenomena, of which (anti-)ferromagnetism is a prominent example. Indeed, magnetic pattern formation has been studied extensively in both solid-state materials and classical liquids. Here, we report on the spontaneous formation of wave-like magnetic patterns in a spinor BoseEinstein condensate, extending those studies into the domain of quantum gases. We observe characteristic modes across a broad range of the magnetic field acting as a control parameter. Our measurements link pattern formation in these quantum systems to specific unstable modes obtainable from linear stability analysis. These investigations open new prospects for controlled studies of symmetry breaking and the appearance of structures in the quantum domain.Bose-Einstein condensates of alkali atoms such as 87 Rb offer unique opportunities to study classical non-linear effects in the quantum regime [1][2][3][4][5] . Governed by many-body quantum mechanics but subject only to weak interactions due to atomic collisions, Bose-Einstein condensates are very well described by a single-particle wavefunction whose dynamics is given by a non-linear Schrödinger equation known as Gross-Pitaevskii equation. Spinor Bose-Einstein condensates 6,7 in addition make use of the non-zero spin and associated magnetic moment of alkali atoms in their internal ground state. Adding the orientation of this spin as a degree of freedom, non-trivial dynamics arises from the spin-dependence of collisional interactions on the one hand, and interaction of the atomic moments with an external magnetic field on the other hand. Although based on fundamentally different interactions this mechanism effectively adds magnetic properties to the quantum gas, similar to the ones in solid state systems.Indeed the dominant spin dependent interaction term in ultracold atomic collisions is proportional to the product of hyperfine spins F 1 · F 2 and thus reminiscent of the Heisenberg model of solid-state magnetism -this analogy motivated the classification of spinor BEC ground states as ferromagnetic and anti-ferromagnetic in previous experiments [8][9][10] . However, it is worth noting that interactions of ultracold atoms are purely local (usually approximated by a δ-potential), in contrast to the next-neighbor interactions common in solid-state models. Further differences arise 1 arXiv:0904.2339v1 [cond-mat.quant-gas] 15 Apr 2009 from the hyperfine nature of the atomic spin, i.e. its composition of nuclear and electronic spins. First of all, its value can be significantly larger than the electron spin S = 1/2, implying a higher dimensional state space with potentially much richer structure and dynamics. Secondly, the internal structure of hyperfine states...