Triboelectric nanogenerators (TENGs) provide the most effective technology for using distributed mechanical energy to power distributed sensor networks. Improving the surface charge density is important to optimizing the performance of TENGs. Unlike electrets with steady-state charges, there is a changing chargedischarge process in the working cycle for materials for TENGs. This article reviews several mechanisms to improve surface charge density by using decay coefficient, transfer time, and effective charge. These mechanisms decouple the physical quantities of charge decay and charge accumulation processes toward higher surface charge density. We also briefly discuss new strategies for improving surface charge density. K E Y W O R D S charge transfer, decay coefficient transfer time, surface charge density, triboelectric nanogenerator 1 INTRODUCTION For the upcoming internet of things era, triboelectric nanogenerator (TENG) provides an effective and environmentally friendly solution for harvesting distributed mechanical energy to power distributed sensor networks. [1,2] TENG combines contact electrification (CE) and electrostatic induction to convert randomly distributed, irregular, and wasted low-frequency mechanical energy into electrical energy. [3] TENGs are applied to mechanical energy harvesting units of self-powered applications in human motion, walking, talking, typing, mechanical triggering, vibration, wind, flowing water, droplet, or even ocean waves into electrical energy. [1,3-7] Triboelectric charges are generated on different surfaces, and mechanical force convert mechanical energy to electrical This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.