2013
DOI: 10.1103/physreva.87.032507
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Dynamic Stark shift of the7Li(2s3s) transition

Abstract: The dynamic dipole polarizabilities for the 3s state of the Li atom are computed using Hylleraas and semiempirical approaches. This enables the calculation of the 7 Li(2s → 3s) Stark shift at photon wavelengths of 610.5 nm and 735.1 nm. They are calculated to be 834.7 (5)

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Cited by 17 publications
(21 citation statements)
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“…Measurement of the magic wavelength here is in some respects in analogous to a measurement of the longest tune-out wavelength for neutral potassium [56]. Zero field shift wavelengths measured in the spin-orbit energy gap of the resonant transition are strongly dominated by the large and opposite polarizability contributions of the two members of the spin-orbit doublet [56,75]. This makes it possible to accurately determine the oscillator strength ratio, i.e.…”
Section: B Dynamic Polarizabilities and Magic Wavelengthsmentioning
confidence: 75%
“…Measurement of the magic wavelength here is in some respects in analogous to a measurement of the longest tune-out wavelength for neutral potassium [56]. Zero field shift wavelengths measured in the spin-orbit energy gap of the resonant transition are strongly dominated by the large and opposite polarizability contributions of the two members of the spin-orbit doublet [56,75]. This makes it possible to accurately determine the oscillator strength ratio, i.e.…”
Section: B Dynamic Polarizabilities and Magic Wavelengthsmentioning
confidence: 75%
“…Light species like lithium offer particularly fruitful interplay between theory and experiment because of the high-accuracy calculational techniques available for few-electron species. Ab initio calculations in atoms with few electrons can account for electron-electron correlations using the variational Hylleraas basis set [43][44][45][46][47]. The Hylleraas calculations are expected to produce the most accurate results in lithium, where they serve as a benchmark for approximation methods applicable to heavier atoms [48].…”
Section: Discussionmentioning
confidence: 99%
“…Precision measurements of TO wavelengths [31][32][33][34][35][36][37][38] may also be used to test all-order atomic theory [24,39,40] and QED [41,42]. Ab initio calculations in simple atoms with three or fewer electrons admit explicit accounting of electron-electron correlations [43][44][45][46][47]. Comparing theory and experiment for lithium serves to benchmark approximation methods applicable to heavier atoms [48].…”
Section: Introductionmentioning
confidence: 99%
“…This is about the same size as the known error in the polarizability in similar calculations for Li, namely, 0.10 a.u. or 0.06% [43,44]. So the assignment of an uncertainty of 0.11 a.u.…”
Section: Uncertainty In the Estimate Of The Tune-out Wavelengthsmentioning
confidence: 99%