Individual behaviors are major contributors to climate change, and changing those behaviors can have a major effect on the magnitude of the climate crisis. To best design interventions to change these behaviors, and target those most likely to change, we must understand the psychological motivations for engaging in them. Previous work has identified environmental beliefs, political orientation, and social expectations as having significant effects on performing pro-environmental behaviors (PEBs). However, this work has tended to focus on lower impact, commonly performed behaviors. In this exploratory study, we evaluate the relevance of these three constructs on predicting individuals’ intention to perform four behaviors previously identified as some of the highest impact individual actions to mitigate greenhouse gas production: driving an electric vehicle, purchasing carbon offsets, switching to a green energy provider, and installing solar panels. Of those three constructs, we find that only social expectations is a strong consistent predictor of intending to perform these high-impact PEBs. These findings suggest that highlighting others performing these behaviors, rather than framing actions in appeals to climate beliefs or targeting those on the political left, may be a particularly effective intervention strategy to drive individual action to mitigate climate change.