Dynamic Fluorescent Metal–Organic Frameworks Utilizing a Flexible Saddle‐Like 3D Linker
Wei‐Miao Zhang,
Zhan Shen,
Miaomiao Wu
et al.
Abstract:Designing single‐component fluorochromic metal–organic frameworks (MOFs) with multiple stages presents a significant challenge in the field of functional and smart MOFs. In this study, this challenge is successfully addressed by designing and synthesizing a novel ligand called cyclooctatetrathiophene‐tetrapyridine (COTTTP), and incorporating it into 3D MOFs known as Zn/Cd‐COTTTP. By exploiting the intrinsic properties of COTTTP, specifically its ability to undergo geometry changes from a bent form to a more pl… Show more
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